Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)

Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)

The title mononuclear complex, [Sm(C7H5O3)2(NO3)(C12H8N2)2], is isostructural with that of other lanthanides. The Sm atom is in a pseudo-bicapped square-antiprismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four from two 2,6-dihydrox...

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Main Authors: Hongxiao Jin, Chiya Wang, Guobo Hu, Dingfeng Jin
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810047136
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spelling doaj-4d13c07c18e74dbbaa5d19ae999b2c092020-11-25T02:01:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1613m161310.1107/S1600536810047136Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)Hongxiao JinChiya WangGuobo HuDingfeng JinThe title mononuclear complex, [Sm(C7H5O3)2(NO3)(C12H8N2)2], is isostructural with that of other lanthanides. The Sm atom is in a pseudo-bicapped square-antiprismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four from two 2,6-dihydroxybenzoate (DHB) ligands and the other two from a nitrate anion. π–π stacking interactions between phen and DHB ligands [centroid–centroid distance = 3.528 (4) and 3.812 (3) Å], and phen and phen ligands [face-to-face separation = 3.420 (10) Å] of adjacent complexes stabilize the crystal structure. Intramolecular O—H...O hydrogen bonds are observed in the DHB ligands. http://scripts.iucr.org/cgi-bin/paper?S1600536810047136
collection DOAJ
language English
format Article
sources DOAJ
author Hongxiao Jin
Chiya Wang
Guobo Hu
Dingfeng Jin
spellingShingle Hongxiao Jin
Chiya Wang
Guobo Hu
Dingfeng Jin
Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
Acta Crystallographica Section E
author_facet Hongxiao Jin
Chiya Wang
Guobo Hu
Dingfeng Jin
author_sort Hongxiao Jin
title Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
title_short Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
title_full Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
title_fullStr Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
title_full_unstemmed Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)samarium(III)
title_sort bis(2,6-dihydroxybenzoato-κ2o1,o1′)(nitrato-κ2o,o′)bis(1,10-phenanthroline-κ2n,n′)samarium(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The title mononuclear complex, [Sm(C7H5O3)2(NO3)(C12H8N2)2], is isostructural with that of other lanthanides. The Sm atom is in a pseudo-bicapped square-antiprismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four from two 2,6-dihydroxybenzoate (DHB) ligands and the other two from a nitrate anion. π–π stacking interactions between phen and DHB ligands [centroid–centroid distance = 3.528 (4) and 3.812 (3) Å], and phen and phen ligands [face-to-face separation = 3.420 (10) Å] of adjacent complexes stabilize the crystal structure. Intramolecular O—H...O hydrogen bonds are observed in the DHB ligands.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810047136
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AT chiyawang bis26dihydroxybenzoatoamp9542o1o1amp8242nitratoamp9542ooamp8242bis110phenanthrolineamp9542nnamp8242samariumiii
AT guobohu bis26dihydroxybenzoatoamp9542o1o1amp8242nitratoamp9542ooamp8242bis110phenanthrolineamp9542nnamp8242samariumiii
AT dingfengjin bis26dihydroxybenzoatoamp9542o1o1amp8242nitratoamp9542ooamp8242bis110phenanthrolineamp9542nnamp8242samariumiii
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