Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate

Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate

In the title complex, [PtCl2(C10H8N2)2]Cl2·H2O, the Pt4+ ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bond...

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Main Authors: Kwang Ha, In-Chul Hwang, Nam-Ho Kim
Format: Article
Language:English
Published: International Union of Crystallography 2009-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809000725
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spelling doaj-4d3cc5e1389647bfa55242d229d605002020-11-24T21:21:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m180m18010.1107/S1600536809000725Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrateKwang HaIn-Chul HwangNam-Ho KimIn the title complex, [PtCl2(C10H8N2)2]Cl2·H2O, the Pt4+ ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays intermolecular hydrogen bonding between the water molecule and the Cl anions. There are intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809000725
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
In-Chul Hwang
Nam-Ho Kim
spellingShingle Kwang Ha
In-Chul Hwang
Nam-Ho Kim
Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
Acta Crystallographica Section E
author_facet Kwang Ha
In-Chul Hwang
Nam-Ho Kim
author_sort Kwang Ha
title Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
title_short Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
title_full Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
title_fullStr Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
title_full_unstemmed Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate
title_sort bis(2,2′-bipyridine-κ2n,n′)dichloridoplatinum(iv) dichloride monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-02-01
description In the title complex, [PtCl2(C10H8N2)2]Cl2·H2O, the Pt4+ ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays intermolecular hydrogen bonding between the water molecule and the Cl anions. There are intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809000725
work_keys_str_mv AT kwangha bis228242bipyridine9542nn8242dichloridoplatinumivdichloridemonohydrate
AT inchulhwang bis228242bipyridine9542nn8242dichloridoplatinumivdichloridemonohydrate
AT namhokim bis228242bipyridine9542nn8242dichloridoplatinumivdichloridemonohydrate
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