4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenol acetone solvate
In the Schiff base molecule of the title compound, C36H48N2O2·C3H6O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. Th...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-03-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808003905 |
Summary: | In the Schiff base molecule of the title compound, C36H48N2O2·C3H6O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. There are two intramolecular O—H...N hydrogen bonds involving the two hydroxy groups, which generate S(6) ring motifs. In the crystal structure, the Schiff base molecules are linked into a chain along the a axis by C—H...π interactions. The acetone solvent molecules are attached to the chain via C—H...O hydrogen bonds. |
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ISSN: | 1600-5368 |