{1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate

{1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate

In the crystal structure of the title compound, [Mo(C27H24N2O2)O2]·1.75CH2Cl2, the MoVI ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand...

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Main Authors: Niaz Monadi, Iran Sheikhshoaie, Abdoreza Rezaeifard, Helen Stoeckli-Evans
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809032759
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spelling doaj-4df25c5e1e3741fbbf51db31a2dab9242020-11-25T01:56:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1124m112510.1107/S1600536809032759{1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvateNiaz MonadiIran SheikhshoaieAbdoreza RezaeifardHelen Stoeckli-EvansIn the crystal structure of the title compound, [Mo(C27H24N2O2)O2]·1.75CH2Cl2, the MoVI ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a distorted octahedral configuration. The compound crystallizes with 1.75 molecules of dichloromethane per complex molecule. In the crystal, symmetry-related molecules are linked by a number of C—H...O interactions involving both the Schiff base ligand and the partly disordered dichloromethane solvent molecules, leading to the formation of a two-dimensional network extending parallel to (101). http://scripts.iucr.org/cgi-bin/paper?S1600536809032759
collection DOAJ
language English
format Article
sources DOAJ
author Niaz Monadi
Iran Sheikhshoaie
Abdoreza Rezaeifard
Helen Stoeckli-Evans
spellingShingle Niaz Monadi
Iran Sheikhshoaie
Abdoreza Rezaeifard
Helen Stoeckli-Evans
{1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
Acta Crystallographica Section E
author_facet Niaz Monadi
Iran Sheikhshoaie
Abdoreza Rezaeifard
Helen Stoeckli-Evans
author_sort Niaz Monadi
title {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
title_short {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
title_full {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
title_fullStr {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
title_full_unstemmed {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
title_sort {1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(vi) dichloromethane 1.75-solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the crystal structure of the title compound, [Mo(C27H24N2O2)O2]·1.75CH2Cl2, the MoVI ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a distorted octahedral configuration. The compound crystallizes with 1.75 molecules of dichloromethane per complex molecule. In the crystal, symmetry-related molecules are linked by a number of C—H...O interactions involving both the Schiff base ligand and the partly disordered dichloromethane solvent molecules, leading to the formation of a two-dimensional network extending parallel to (101).
url http://scripts.iucr.org/cgi-bin/paper?S1600536809032759
work_keys_str_mv AT niazmonadi 11amp824222dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT iransheikhshoaie 11amp824222dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT abdorezarezaeifard 11amp824222dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT helenstoecklievans 11amp824222dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
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