| Summary: | In the crystal structure of title compound, C9H10N2OS, there are two symmetry-independent molecules, each having an intramolecular N—H...O hydrogen bond generating an S(6) ring motif. The benzene rings and the virtually planar acetylthoiurea fragments [r.m.s. deviations = 0.0045 and 0.0341 Å] are oriented at dihedral angles of 50.71 (6) and 62.79 (6)° in the two molecules. In the crystal, N—H...S and N—H...O hydrogen bonds link molecules via cyclic R22(8) and R22(12) motifs into a one-dimensional polymeric network extending along [101]. The intra- and intermolecular N—H...O interactions are part of a three-center hydrogen bond. A C—H...S interaction also occurs.
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