catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]

catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]

In the title complex, {[Cd(CH3COO)2(C11H8N2O)(H2O)]·2H2O}n, the CdII ion adopts an O5N2 pentagonal–bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyrid...

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Main Authors: Zhi-Wei Wang, Ai-Min Li, Ya Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812019101
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spelling doaj-4ebaff44a0b140559ce0e5d6257b57722020-11-24T21:05:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m723m72310.1107/S1600536812019101catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]Zhi-Wei WangAi-Min LiYa ZhangIn the title complex, {[Cd(CH3COO)2(C11H8N2O)(H2O)]·2H2O}n, the CdII ion adopts an O5N2 pentagonal–bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ2-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O—H...O hydrogen bonds involving the lattice water molecules connect these chains into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812019101
collection DOAJ
language English
format Article
sources DOAJ
author Zhi-Wei Wang
Ai-Min Li
Ya Zhang
spellingShingle Zhi-Wei Wang
Ai-Min Li
Ya Zhang
catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
Acta Crystallographica Section E
author_facet Zhi-Wei Wang
Ai-Min Li
Ya Zhang
author_sort Zhi-Wei Wang
title catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
title_short catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
title_full catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
title_fullStr catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
title_full_unstemmed catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
title_sort catena-poly[[[bis(acetato-κ2o,o′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2n:n′] dihydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the title complex, {[Cd(CH3COO)2(C11H8N2O)(H2O)]·2H2O}n, the CdII ion adopts an O5N2 pentagonal–bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ2-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O—H...O hydrogen bonds involving the lattice water molecules connect these chains into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812019101
work_keys_str_mv AT zhiweiwang catenapolybisacetatoamp9542ooamp8242aquacadmiumamp956pyridin3ylpyridin4ylmethanoneamp9542nnamp8242dihydrate
AT aiminli catenapolybisacetatoamp9542ooamp8242aquacadmiumamp956pyridin3ylpyridin4ylmethanoneamp9542nnamp8242dihydrate
AT yazhang catenapolybisacetatoamp9542ooamp8242aquacadmiumamp956pyridin3ylpyridin4ylmethanoneamp9542nnamp8242dihydrate
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