(η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate

(η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate

In the title compound, [RuCl(C6H6)(C10H8N2)]Cl·1.5CH4O, the RuII atom is in a distorted octahedral environment coordinated by an η6-benzene ring, a chelating 2,2′-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol m...

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Main Author: Matthew I. J. Polson
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807066858
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spelling doaj-4ee358b1e2a8429d916899843313de5b2020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m256m25610.1107/S1600536807066858(η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvateMatthew I. J. PolsonIn the title compound, [RuCl(C6H6)(C10H8N2)]Cl·1.5CH4O, the RuII atom is in a distorted octahedral environment coordinated by an η6-benzene ring, a chelating 2,2′-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol molecules, one of which is disordered about a centre of inversion with an occupancy of 0.5. It is an example of a ruthenium complex with a less sterically congested environment than in similar derivatives. In the crystal structure, O—H...Cl hydrogen bonds, together with π–π stacking interactions [centroid–centroid distances of 3.472Å(2) Å], stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536807066858
collection DOAJ
language English
format Article
sources DOAJ
author Matthew I. J. Polson
spellingShingle Matthew I. J. Polson
(η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
Acta Crystallographica Section E
author_facet Matthew I. J. Polson
author_sort Matthew I. J. Polson
title (η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
title_short (η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
title_full (η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
title_fullStr (η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
title_full_unstemmed (η6-Benzene)(2,2′-bipyridine-κ2N,N′)chloridoruthenium(II) chloride methanol sesquisolvate
title_sort (η6-benzene)(2,2′-bipyridine-κ2n,n′)chloridoruthenium(ii) chloride methanol sesquisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the title compound, [RuCl(C6H6)(C10H8N2)]Cl·1.5CH4O, the RuII atom is in a distorted octahedral environment coordinated by an η6-benzene ring, a chelating 2,2′-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol molecules, one of which is disordered about a centre of inversion with an occupancy of 0.5. It is an example of a ruthenium complex with a less sterically congested environment than in similar derivatives. In the crystal structure, O—H...Cl hydrogen bonds, together with π–π stacking interactions [centroid–centroid distances of 3.472Å(2) Å], stabilize the structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807066858
work_keys_str_mv AT matthewijpolson 9516benzene228242bipyridine9542nn8242chloridorutheniumiichloridemethanolsesquisolvate
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