2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate
The structure of the title hydrated molecular salt, C10H8NS+·Cl−·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alte...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2020-11-01
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Series: | IUCrData |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620014650 |
Summary: | The structure of the title hydrated molecular salt, C10H8NS+·Cl−·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alternating Cl− anions and H2O molecules connected by O—H...O hydrogen bonds. The cation shows whole-molecule disorder over two flipped orientations in a 0.853 (3):0.147 (3) ratio. |
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ISSN: | 2414-3146 |