2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate
The structure of the title hydrated molecular salt, C10H8NS+·Cl−·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alte...
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International Union of Crystallography
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doaj-4f2378a328c643cfb7e123c4c01abb642021-04-22T09:45:09ZengInternational Union of CrystallographyIUCrData2414-31462020-11-01511x20146510.1107/S2414314620014650hb43682H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrateMadeleine A. Ehweiner0Ferdinand Belaj1Nadia C. Mösch-Zanetti2University of Graz, Institute of Chemistry, Schubertstr. 1, 8010 Graz, AustriaUniversity of Graz, Institute of Chemistry, Schubertstr. 1, 8010 Graz, AustriaUniversity of Graz, Institute of Chemistry, Schubertstr. 1, 8010 Graz, AustriaThe structure of the title hydrated molecular salt, C10H8NS+·Cl−·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alternating Cl− anions and H2O molecules connected by O—H...O hydrogen bonds. The cation shows whole-molecule disorder over two flipped orientations in a 0.853 (3):0.147 (3) ratio.http://scripts.iucr.org/cgi-bin/paper?S2414314620014650crystal structurequinolinehydrogen bonding |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Madeleine A. Ehweiner Ferdinand Belaj Nadia C. Mösch-Zanetti |
spellingShingle |
Madeleine A. Ehweiner Ferdinand Belaj Nadia C. Mösch-Zanetti 2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate IUCrData crystal structure quinoline hydrogen bonding |
author_facet |
Madeleine A. Ehweiner Ferdinand Belaj Nadia C. Mösch-Zanetti |
author_sort |
Madeleine A. Ehweiner |
title |
2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
title_short |
2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
title_full |
2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
title_fullStr |
2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
title_full_unstemmed |
2H-[1,3]Thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
title_sort |
2h-[1,3]thiazolo[5,4,3-ij]quinolin-3-ium chloride monohydrate |
publisher |
International Union of Crystallography |
series |
IUCrData |
issn |
2414-3146 |
publishDate |
2020-11-01 |
description |
The structure of the title hydrated molecular salt, C10H8NS+·Cl−·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)–3.356 (4) Å] and features chains built by alternating Cl− anions and H2O molecules connected by O—H...O hydrogen bonds. The cation shows whole-molecule disorder over two flipped orientations in a 0.853 (3):0.147 (3) ratio. |
topic |
crystal structure quinoline hydrogen bonding |
url |
http://scripts.iucr.org/cgi-bin/paper?S2414314620014650 |
work_keys_str_mv |
AT madeleineaehweiner 2h13thiazolo543ijquinolin3iumchloridemonohydrate AT ferdinandbelaj 2h13thiazolo543ijquinolin3iumchloridemonohydrate AT nadiacmoschzanetti 2h13thiazolo543ijquinolin3iumchloridemonohydrate |
_version_ |
1721514663134363648 |