Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI)
In the title salt, [Eu(C3H7NO)8][PMo12O40], the asymmetric unit comprises one α-Keggin-type [PMo12O40]3− polyoxidometalate anion and one distorted dodecahedral [Eu(C3H7NO)8]3+ complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexagonally arranged rows extending pa...
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International Union of Crystallography
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016003546 |
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doaj-4f407955be56498cbab5feec420eb4c92020-11-24T23:41:25ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-04-0172444845110.1107/S2056989016003546wm5274Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI)Yassine Ghandour0Imen Hammami1Shabir Najmudin2Cecilia Bonifácio3Mohamed Salah Belkhiria4Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaLaboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaFaculdade de Medicina, Veterinària, Universidade Tecnica de Lisboa, Avenida da Universidade Tecnica, 1300-477 Lisboa, PortugalREQUIMTE/CQFB Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, PortugalLaboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaIn the title salt, [Eu(C3H7NO)8][PMo12O40], the asymmetric unit comprises one α-Keggin-type [PMo12O40]3− polyoxidometalate anion and one distorted dodecahedral [Eu(C3H7NO)8]3+ complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexagonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H...O hydrogen-bonding interactions, leading to the formation of a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S2056989016003546crystal structureα-Keggin-type [PMo12O40]3− polyanioneuropiumIR spectroscopy |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Yassine Ghandour Imen Hammami Shabir Najmudin Cecilia Bonifácio Mohamed Salah Belkhiria |
| spellingShingle |
Yassine Ghandour Imen Hammami Shabir Najmudin Cecilia Bonifácio Mohamed Salah Belkhiria Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) Acta Crystallographica Section E: Crystallographic Communications crystal structure α-Keggin-type [PMo12O40]3− polyanion europium IR spectroscopy |
| author_facet |
Yassine Ghandour Imen Hammami Shabir Najmudin Cecilia Bonifácio Mohamed Salah Belkhiria |
| author_sort |
Yassine Ghandour |
| title |
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) |
| title_short |
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) |
| title_full |
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) |
| title_fullStr |
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) |
| title_full_unstemmed |
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI) |
| title_sort |
crystal structure of octakis(n,n-dimethylformamide-κo)europium(iii) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(vi) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2016-04-01 |
| description |
In the title salt, [Eu(C3H7NO)8][PMo12O40], the asymmetric unit comprises one α-Keggin-type [PMo12O40]3− polyoxidometalate anion and one distorted dodecahedral [Eu(C3H7NO)8]3+ complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexagonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H...O hydrogen-bonding interactions, leading to the formation of a three-dimensional network structure. |
| topic |
crystal structure α-Keggin-type [PMo12O40]3− polyanion europium IR spectroscopy |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2056989016003546 |
| work_keys_str_mv |
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