catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]

catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]

In the title coordination polymer, [Mn(C6Cl2O4)(C2H5OH)2]n, the MnII atom and the chloranilate [systematic name: 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olate)] ion lie on crystallographic inversion centers. The geometry around the MnII atom is a distorted octahedron involving four O atoms...

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Main Authors: Seiya Tanaka, Akiko Himegi, Tomomi Ohishi, Akira Fuyuhiro, Satoshi Kawata
Format: Article
Language:English
Published: International Union of Crystallography 2014-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814002396
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spelling doaj-5117490e59b741a0aaf2274e27fce5392020-11-24T21:30:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-03-01703m90m9110.1107/S1600536814002396is5335catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]Seiya Tanaka0Akiko Himegi1Tomomi Ohishi2Akira Fuyuhiro3Satoshi Kawata4Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, JapanDepartment of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, JapanDepartment of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, JapanIn the title coordination polymer, [Mn(C6Cl2O4)(C2H5OH)2]n, the MnII atom and the chloranilate [systematic name: 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olate)] ion lie on crystallographic inversion centers. The geometry around the MnII atom is a distorted octahedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol molecules. The chloranilate ion serves as a bridging ligand between the MnII ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H...O hydrogen bonds between the apically coordinating ethanol molecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S1600536814002396
collection DOAJ
language English
format Article
sources DOAJ
author Seiya Tanaka
Akiko Himegi
Tomomi Ohishi
Akira Fuyuhiro
Satoshi Kawata
spellingShingle Seiya Tanaka
Akiko Himegi
Tomomi Ohishi
Akira Fuyuhiro
Satoshi Kawata
catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
Acta Crystallographica Section E
author_facet Seiya Tanaka
Akiko Himegi
Tomomi Ohishi
Akira Fuyuhiro
Satoshi Kawata
author_sort Seiya Tanaka
title catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
title_short catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
title_full catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
title_fullStr catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
title_full_unstemmed catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O1,O6:O3,O4]
title_sort catena-poly[[bis(ethanol-κo)manganese(ii)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4o1,o6:o3,o4]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-03-01
description In the title coordination polymer, [Mn(C6Cl2O4)(C2H5OH)2]n, the MnII atom and the chloranilate [systematic name: 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olate)] ion lie on crystallographic inversion centers. The geometry around the MnII atom is a distorted octahedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol molecules. The chloranilate ion serves as a bridging ligand between the MnII ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H...O hydrogen bonds between the apically coordinating ethanol molecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814002396
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