1-Nitro-4-(1-propyn-1-yl)benzene

1-Nitro-4-(1-propyn-1-yl)benzene

The title compound, C9H7NO2, was prepared by alkynylation of 4-iodonitrobenzene with 1,3-dilithiopropyne in the presence of 1 equivalent of CuI and catalytic amounts of Pd(PPh3)2Cl2. The complete molecule is generated by crystallographic twofold symmetry with the C—N and C—C[triple-bond]C—C units ly...

Full description

Bibliographic Details
Main Authors: Cristian Saul Campos Fernandez, Leslie W. Pineda, Jorge Cabezas Pizarro
Format: Article
Language:English
Published: International Union of Crystallography 2019-11-01
Series:IUCrData
Subjects:
crystal structure
alkynes
1,3-dilithiopropyne
propargylation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619015852
id doaj-5119e1c78a2a4e9b9a76628c2bc7dbaa
record_format Article
spelling doaj-5119e1c78a2a4e9b9a76628c2bc7dbaa2020-11-25T02:42:26ZengInternational Union of CrystallographyIUCrData2414-31462019-11-01411x19158510.1107/S2414314619015852hb43271-Nitro-4-(1-propyn-1-yl)benzeneCristian Saul Campos Fernandez0Leslie W. Pineda1Jorge Cabezas Pizarro2Escuela de Química, Universidad de Costa Rica, San José, 11501-2060, Costa RicaEscuela de Química, Universidad de Costa Rica, San José, 11501-2060, Costa RicaEscuela de Química, Universidad de Costa Rica, San José, 11501-2060, Costa RicaThe title compound, C9H7NO2, was prepared by alkynylation of 4-iodonitrobenzene with 1,3-dilithiopropyne in the presence of 1 equivalent of CuI and catalytic amounts of Pd(PPh3)2Cl2. The complete molecule is generated by crystallographic twofold symmetry with the C—N and C—C[triple-bond]C—C units lying on the rotation axis. No directional interactions beyond normal van der Waals contacts could be identified in the packing.http://scripts.iucr.org/cgi-bin/paper?S2414314619015852crystal structurealkynes1,3-dilithiopropynepropargylation
collection DOAJ
language English
format Article
sources DOAJ
author Cristian Saul Campos Fernandez
Leslie W. Pineda
Jorge Cabezas Pizarro
spellingShingle Cristian Saul Campos Fernandez
Leslie W. Pineda
Jorge Cabezas Pizarro
1-Nitro-4-(1-propyn-1-yl)benzene
IUCrData
crystal structure
alkynes
1,3-dilithiopropyne
propargylation
author_facet Cristian Saul Campos Fernandez
Leslie W. Pineda
Jorge Cabezas Pizarro
author_sort Cristian Saul Campos Fernandez
title 1-Nitro-4-(1-propyn-1-yl)benzene
title_short 1-Nitro-4-(1-propyn-1-yl)benzene
title_full 1-Nitro-4-(1-propyn-1-yl)benzene
title_fullStr 1-Nitro-4-(1-propyn-1-yl)benzene
title_full_unstemmed 1-Nitro-4-(1-propyn-1-yl)benzene
title_sort 1-nitro-4-(1-propyn-1-yl)benzene
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2019-11-01
description The title compound, C9H7NO2, was prepared by alkynylation of 4-iodonitrobenzene with 1,3-dilithiopropyne in the presence of 1 equivalent of CuI and catalytic amounts of Pd(PPh3)2Cl2. The complete molecule is generated by crystallographic twofold symmetry with the C—N and C—C[triple-bond]C—C units lying on the rotation axis. No directional interactions beyond normal van der Waals contacts could be identified in the packing.
topic crystal structure
alkynes
1,3-dilithiopropyne
propargylation
url http://scripts.iucr.org/cgi-bin/paper?S2414314619015852
work_keys_str_mv AT cristiansaulcamposfernandez 1nitro41propyn1ylbenzene
AT lesliewpineda 1nitro41propyn1ylbenzene
AT jorgecabezaspizarro 1nitro41propyn1ylbenzene
_version_ 1724773999083257856

Similar Items