Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)

Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)

The title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two MnII atoms are bridged by two O atoms of two different 2-benzoylbenzoate ligands, each MnII atom being further coordinated by two 2,2′-bipyr...

Full description

Bibliographic Details
Main Author: Ibrahim Kani
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
manganese(II) complex
benzoylbenzoate
2,2′-bipyridine
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015023671
id doaj-51b619ebe2d749a8a8ca474777f16844
record_format Article
spelling doaj-51b619ebe2d749a8a8ca474777f168442020-11-24T22:32:24ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112m265m26610.1107/S2056989015023671bg2577Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)Ibrahim Kani0Anadolu University, Faculty of Sciences, Department of Chemistry, 26470 Eskişehir, TurkeyThe title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two MnII atoms are bridged by two O atoms of two different 2-benzoylbenzoate ligands, each MnII atom being further coordinated by two 2,2′-bipyridine (bipy) ligands in a distorted octahedral environment. Within the binuclear molecule, the Mn...Mn separation is 4.513 (7) Å. Intermolecular C—H...O and C—H... π interactions link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989015023671crystal structuremanganese(II) complexbenzoylbenzoate2,2′-bipyridinehydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Ibrahim Kani
spellingShingle Ibrahim Kani
Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
manganese(II) complex
benzoylbenzoate
2,2′-bipyridine
hydrogen bonding
author_facet Ibrahim Kani
author_sort Ibrahim Kani
title Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
title_short Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
title_full Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
title_fullStr Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
title_full_unstemmed Crystal structure of bis(μ-2-benzoylbenzoato-κ2O:O′)bis[bis(2,2′-bipyridine-κ2N,N′)manganese(II)] bis(perchlorate)
title_sort crystal structure of bis(μ-2-benzoylbenzoato-κ2o:o′)bis[bis(2,2′-bipyridine-κ2n,n′)manganese(ii)] bis(perchlorate)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-12-01
description The title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two MnII atoms are bridged by two O atoms of two different 2-benzoylbenzoate ligands, each MnII atom being further coordinated by two 2,2′-bipyridine (bipy) ligands in a distorted octahedral environment. Within the binuclear molecule, the Mn...Mn separation is 4.513 (7) Å. Intermolecular C—H...O and C—H... π interactions link the molecules into a three-dimensional network.
topic crystal structure
manganese(II) complex
benzoylbenzoate
2,2′-bipyridine
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S2056989015023671
work_keys_str_mv AT ibrahimkani crystalstructureofbism2benzoylbenzoatok2oobisbis22bipyridinek2nnmanganeseiibisperchlorate
_version_ 1725734201514262528

Similar Items