Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, seconda...

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Main Authors:	Shi-juan Liu, Miao Zhang, Rong Lu, Xiu-ying Li, Guang-bo Che
Format:	Article
Language:	English
Published:	MDPI AG 2018-07-01
Series:	Molecules
Subjects:	sodium copper chlorophyllin oxidation alcohols chemoselectivity water
Online Access:	http://www.mdpi.com/1420-3049/23/8/1883

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spelling	doaj-51f20245e85a407182f445ff65b9415c2020-11-25T01:03:46ZengMDPI AGMolecules1420-30492018-07-01238188310.3390/molecules23081883molecules23081883Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in WaterShi-juan Liu0Miao Zhang1Rong Lu2Xiu-ying Li3Guang-bo Che4Key Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun 130103, ChinaCollege of Chemistry, Jilin Normal University, Siping 136000, ChinaCollege of Chemistry, Jilin Normal University, Siping 136000, ChinaKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun 130103, ChinaKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun 130103, ChinaWe report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.http://www.mdpi.com/1420-3049/23/8/1883sodium copper chlorophyllinoxidationalcoholschemoselectivitywater
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Shi-juan Liu Miao Zhang Rong Lu Xiu-ying Li Guang-bo Che
spellingShingle	Shi-juan Liu Miao Zhang Rong Lu Xiu-ying Li Guang-bo Che Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water Molecules sodium copper chlorophyllin oxidation alcohols chemoselectivity water
author_facet	Shi-juan Liu Miao Zhang Rong Lu Xiu-ying Li Guang-bo Che
author_sort	Shi-juan Liu
title	Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_short	Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_full	Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_fullStr	Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_full_unstemmed	Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_sort	sodium copper chlorophyllin catalyzed chemoselective oxidation of benzylic alcohols and diarylmethanes in water
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2018-07-01
description	We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.
topic	sodium copper chlorophyllin oxidation alcohols chemoselectivity water
url	http://www.mdpi.com/1420-3049/23/8/1883
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Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

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