Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
Mechanistic insight into enantioselective reactions at intrinsically chiral surfaces can be challenging to obtain. Here the catalytic activity of Pd1- and Pd3-terminated PdGa{111} surfaces is shown to differ substantially, with Pd1-terminated surfaces promoting on-surface azide– alkyne cycloaddition...
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Bibliographic Details
| Main Authors: |
Samuel Stolz,
Michael Bauer,
Carlo A. Pignedoli,
Nils Krane,
Max Bommert,
Elia Turco,
Nicolò Bassi,
Amogh Kinikar,
Néstor Merino-Dìez,
Roland Hany,
Harald Brune,
Oliver Gröning,
Roland Widmer |
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| Format: | Article
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| Language: | English |
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| Published: |
Nature Publishing Group
2021-04-01
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| Series: | Communications Chemistry
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| Online Access: | https://doi.org/10.1038/s42004-021-00488-0
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