Acetylation of alcohols and amines catalyzed by onion peel ash under a base- and solvent-free condition

This manuscript describes a facile and environmentally benign protocol for the acetylation of various alcohol and amines catalyzed by onion peel ash under a base- and solvent-free condition. Various acetates were successfully prepared from the alcohols and amines using onion peel ash as a catalyst...

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Bibliographic Details
Main Authors: Poh Wai Chia, Poh Seng Chee, Noor Wini Mazla, Fu Siong Julius Yong, Mohd Zul Helmi Rozaini, Su-Yin Kan
Format: Article
Language:English
Published: Prince of Songkla University 2020-06-01
Series:Songklanakarin Journal of Science and Technology (SJST)
Subjects:
Online Access:https://rdo.psu.ac.th/sjstweb/journal/42-3/15.pdf
Description
Summary:This manuscript describes a facile and environmentally benign protocol for the acetylation of various alcohol and amines catalyzed by onion peel ash under a base- and solvent-free condition. Various acetates were successfully prepared from the alcohols and amines using onion peel ash as a catalyst and the end-products were obtained in good to excellent yields (76−96%). The current reported protocol complies with green chemistry principles, such as a base- and solvent-free condition, mildness of the reaction, and a recyclable catalytic system up to four times. Furthermore, the current method allows the management of the abundant onion peel bio-waste into a more useful catalyst in the field of organic synthesis. The transformations of bio-wastes into catalysts for organic reactions are of interest and highly sought after by scientists to meet the goal for a more sustainable chemistry in the near future.
ISSN:0125-3395