Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase

Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase

A highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield...

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Main Authors: Zhengyin Du, Xiaohong Wei, Wenwen Zhang, Yuanmin Zhang, Qunji Xue
Format: Article
Language:English
Published: Hindawi Limited 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/989285
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spelling doaj-52e99dc11bb24ceaa1b86e411366c0152020-11-24T20:51:52ZengHindawi LimitedJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/989285989285Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous PhaseZhengyin Du0Xiaohong Wei1Wenwen Zhang2Yuanmin Zhang3Qunji Xue4Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaA highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield of up to 99% with complete conversion of anilines.http://dx.doi.org/10.1155/2013/989285
collection DOAJ
language English
format Article
sources DOAJ
author Zhengyin Du
Xiaohong Wei
Wenwen Zhang
Yuanmin Zhang
Qunji Xue
spellingShingle Zhengyin Du
Xiaohong Wei
Wenwen Zhang
Yuanmin Zhang
Qunji Xue
Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
Journal of Chemistry
author_facet Zhengyin Du
Xiaohong Wei
Wenwen Zhang
Yuanmin Zhang
Qunji Xue
author_sort Zhengyin Du
title Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
title_short Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
title_full Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
title_fullStr Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
title_full_unstemmed Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
title_sort catalyst-free and highly selective n,n-diallylation of anilines in aqueous phase
publisher Hindawi Limited
series Journal of Chemistry
issn 2090-9063
2090-9071
publishDate 2013-01-01
description A highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield of up to 99% with complete conversion of anilines.
url http://dx.doi.org/10.1155/2013/989285
work_keys_str_mv AT zhengyindu catalystfreeandhighlyselectivenndiallylationofanilinesinaqueousphase
AT xiaohongwei catalystfreeandhighlyselectivenndiallylationofanilinesinaqueousphase
AT wenwenzhang catalystfreeandhighlyselectivenndiallylationofanilinesinaqueousphase
AT yuanminzhang catalystfreeandhighlyselectivenndiallylationofanilinesinaqueousphase
AT qunjixue catalystfreeandhighlyselectivenndiallylationofanilinesinaqueousphase
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