catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
In the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a dis...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2009-08-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809024714 |
id |
doaj-535d46a9ccbc41a59a1566efd6b7c226 |
---|---|
record_format |
Article |
spelling |
doaj-535d46a9ccbc41a59a1566efd6b7c2262020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m876m87610.1107/S1600536809024714catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]Li-Ying HanHu ZangDa-Jun SunYa-Ping LiIn the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a distorted octahedral environment. The two 4,4′-ethylenedibenzoate dianions are located on inversion centres bridging two neighboring CdII centres. O—H...O hydrogen-bonding interactions further stabilize the crystal structure. The DMF molecule is equally disordered about a center of inversion. http://scripts.iucr.org/cgi-bin/paper?S1600536809024714 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Li-Ying Han Hu Zang Da-Jun Sun Ya-Ping Li |
spellingShingle |
Li-Ying Han Hu Zang Da-Jun Sun Ya-Ping Li catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] Acta Crystallographica Section E |
author_facet |
Li-Ying Han Hu Zang Da-Jun Sun Ya-Ping Li |
author_sort |
Li-Ying Han |
title |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] |
title_short |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] |
title_full |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] |
title_fullStr |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] |
title_full_unstemmed |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate] |
title_sort |
catena-poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(ii)]-μ-4,4′-ethylenedibenzoato] n,n-dimethylformamide hemisolvate] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-08-01 |
description |
In the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a distorted octahedral environment. The two 4,4′-ethylenedibenzoate dianions are located on inversion centres bridging two neighboring CdII centres. O—H...O hydrogen-bonding interactions further stabilize the crystal structure. The DMF molecule is equally disordered about a center of inversion. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809024714 |
work_keys_str_mv |
AT liyinghan catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate AT huzang catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate AT dajunsun catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate AT yapingli catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate |
_version_ |
1724756209037213696 |