catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]

catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]

In the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a dis...

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Main Authors: Li-Ying Han, Hu Zang, Da-Jun Sun, Ya-Ping Li
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809024714
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spelling doaj-535d46a9ccbc41a59a1566efd6b7c2262020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m876m87610.1107/S1600536809024714catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]Li-Ying HanHu ZangDa-Jun SunYa-Ping LiIn the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a distorted octahedral environment. The two 4,4′-ethylenedibenzoate dianions are located on inversion centres bridging two neighboring CdII centres. O—H...O hydrogen-bonding interactions further stabilize the crystal structure. The DMF molecule is equally disordered about a center of inversion. http://scripts.iucr.org/cgi-bin/paper?S1600536809024714
collection DOAJ
language English
format Article
sources DOAJ
author Li-Ying Han
Hu Zang
Da-Jun Sun
Ya-Ping Li
spellingShingle Li-Ying Han
Hu Zang
Da-Jun Sun
Ya-Ping Li
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
Acta Crystallographica Section E
author_facet Li-Ying Han
Hu Zang
Da-Jun Sun
Ya-Ping Li
author_sort Li-Ying Han
title catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
title_short catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
title_full catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
title_fullStr catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
title_full_unstemmed catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
title_sort catena-poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(ii)]-μ-4,4′-ethylenedibenzoato] n,n-dimethylformamide hemisolvate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description In the title compound, [Cd(C16H10O4)(C14H8N4)(H2O)]·0.5C3H7NO, the CdII atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxylate O atoms from two different 4,4′-ethylenedibenzoate ligands, and one water molecule in a distorted octahedral environment. The two 4,4′-ethylenedibenzoate dianions are located on inversion centres bridging two neighboring CdII centres. O—H...O hydrogen-bonding interactions further stabilize the crystal structure. The DMF molecule is equally disordered about a center of inversion.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809024714
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AT huzang catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate
AT dajunsun catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate
AT yapingli catenapolyaquapyrazino23f110phenanthrolinecadiumiiamp95644amp8242ethylenedibenzoatonndimethylformamidehemisolvate
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