A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms

Raw lacquer (RL), ethanol being used as the solvent, was added to polyvinyl pyrrolidone (PVP) and then electrospun into RL/PVP nanofilms. Manufacturing parameters such as RL/PVP ratio, voltage, flow velocity, needle type, and the distance between syringe and the collection board were systematically...

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Main Authors: Kunlin Wu, Ding Zhang, Minghua Liu, Qi Lin, Bing-Chiuan Shiu
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/9/1723
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spelling doaj-5372f6371915429bb83ad3d5ca3a24972020-11-25T03:44:00ZengMDPI AGNanomaterials2079-49912020-08-01101723172310.3390/nano10091723A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP NanofilmsKunlin Wu0Ding Zhang1Minghua Liu2Qi Lin3Bing-Chiuan Shiu4Fujian Engineering and Research Center of New Chinese Lacquer Materials, Ocean College, Minjiang University, Fuzhou 350108, ChinaFujian Engineering and Research Center of New Chinese Lacquer Materials, Ocean College, Minjiang University, Fuzhou 350108, ChinaCollege of Environment and Resources, Fuzhou University, Fuzhou 350108, ChinaFujian Engineering and Research Center of New Chinese Lacquer Materials, Ocean College, Minjiang University, Fuzhou 350108, ChinaFujian Engineering and Research Center of New Chinese Lacquer Materials, Ocean College, Minjiang University, Fuzhou 350108, ChinaRaw lacquer (RL), ethanol being used as the solvent, was added to polyvinyl pyrrolidone (PVP) and then electrospun into RL/PVP nanofilms. Manufacturing parameters such as RL/PVP ratio, voltage, flow velocity, needle type, and the distance between syringe and the collection board were systematically investigated. A scanning electronic microscope (SEM) was used to observe the surface morphology of nanofilms; the block drop method was used to measure the water contact angle; the mechanical properties of RL/PVP nanofilms of different proportions were tested by universal material testing machine; and Fourier-transform infrared spectroscopy (FT-IR) was used to characterize the structure. Based on the water resistance and acid resistance measurements, the proposed nanofilms demonstrated to be water and acid resistant were successfully produced. The results show that PVP that melts in water becomes incompatible with water after adding raw lacquer, and the acid resistance is greatly improved. Furthermore, the smaller the fiber diameter, the better the mechanical properties of the nanofilms are under low ratio of RL/PVP. With a high proportion of RL/PVP, the inner structure of the nanofilm is denser, and the water resistance and acid resistance are better. The dense structure can protect the inner material of the nanofilms.https://www.mdpi.com/2079-4991/10/9/1723raw lacquer (RL)polyvinyl pyrrolidone (PVP)electrospinningnanofibers
collection DOAJ
language English
format Article
sources DOAJ
author Kunlin Wu
Ding Zhang
Minghua Liu
Qi Lin
Bing-Chiuan Shiu
spellingShingle Kunlin Wu
Ding Zhang
Minghua Liu
Qi Lin
Bing-Chiuan Shiu
A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
Nanomaterials
raw lacquer (RL)
polyvinyl pyrrolidone (PVP)
electrospinning
nanofibers
author_facet Kunlin Wu
Ding Zhang
Minghua Liu
Qi Lin
Bing-Chiuan Shiu
author_sort Kunlin Wu
title A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
title_short A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
title_full A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
title_fullStr A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
title_full_unstemmed A Study on the Improvement of Using Raw Lacquer and Electrospinning on Properties of PVP Nanofilms
title_sort study on the improvement of using raw lacquer and electrospinning on properties of pvp nanofilms
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2020-08-01
description Raw lacquer (RL), ethanol being used as the solvent, was added to polyvinyl pyrrolidone (PVP) and then electrospun into RL/PVP nanofilms. Manufacturing parameters such as RL/PVP ratio, voltage, flow velocity, needle type, and the distance between syringe and the collection board were systematically investigated. A scanning electronic microscope (SEM) was used to observe the surface morphology of nanofilms; the block drop method was used to measure the water contact angle; the mechanical properties of RL/PVP nanofilms of different proportions were tested by universal material testing machine; and Fourier-transform infrared spectroscopy (FT-IR) was used to characterize the structure. Based on the water resistance and acid resistance measurements, the proposed nanofilms demonstrated to be water and acid resistant were successfully produced. The results show that PVP that melts in water becomes incompatible with water after adding raw lacquer, and the acid resistance is greatly improved. Furthermore, the smaller the fiber diameter, the better the mechanical properties of the nanofilms are under low ratio of RL/PVP. With a high proportion of RL/PVP, the inner structure of the nanofilm is denser, and the water resistance and acid resistance are better. The dense structure can protect the inner material of the nanofilms.
topic raw lacquer (RL)
polyvinyl pyrrolidone (PVP)
electrospinning
nanofibers
url https://www.mdpi.com/2079-4991/10/9/1723
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