Diaquabis(1H-imidazole-κN3)bis(4-nitrobenzoato-κO1)cadmium

Diaquabis(1H-imidazole-κN3)bis(4-nitrobenzoato-κO1)cadmium

In the centrosymmetric title compound, [Cd(C7H4NO4)2(C3H4N2)2(H2O)2], the CdII atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H...O hydrogen bond. I...

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Bibliographic Details
Main Authors: Yan-Li Mao, Xiao-Ke Yu, Jian-Li Lin
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812033739
Description
Summary:In the centrosymmetric title compound, [Cd(C7H4NO4)2(C3H4N2)2(H2O)2], the CdII atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H...O hydrogen bond. Intermolecular O—H...O and C—H...O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H...O interactions into a weakly connected three-dimensional supramolecular framework.
ISSN:1600-5368

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