Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}

Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}

In the centrosymmetric title binuclear complex, [Zn2(C8H7O2)4(C7H10N2)2], the Zn atoms [Zn...Zn = 3.0287 (6) Å] are bridged by four 4-methylbenzoate ligands. The four nearest O atoms around each ZnII atom form a distorted square-planar arrangement with the di...

Full description

Bibliographic Details
Main Authors: Zhu-Ping Xiao, Xin-Hua Liu, Lin-Shan Bai
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809027603
id doaj-572ee2ca3332449db0633cecd41b5d96
record_format Article
spelling doaj-572ee2ca3332449db0633cecd41b5d962020-11-24T22:08:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m948m94910.1107/S1600536809027603Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}Zhu-Ping XiaoXin-Hua LiuLin-Shan BaiIn the centrosymmetric title binuclear complex, [Zn2(C8H7O2)4(C7H10N2)2], the Zn atoms [Zn...Zn = 3.0287 (6) Å] are bridged by four 4-methylbenzoate ligands. The four nearest O atoms around each ZnII atom form a distorted square-planar arrangement with the distorted square-pyramidal coordination completed by the pyridine N atom of the 4-(dimethylamino)pyridine ligand. In the crystal structure, weak intermolecular C—H...O interactions link the molecules into infinite chains. The chains are further linked by weak C—H...π interactions, forming a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536809027603
collection DOAJ
language English
format Article
sources DOAJ
author Zhu-Ping Xiao
Xin-Hua Liu
Lin-Shan Bai
spellingShingle Zhu-Ping Xiao
Xin-Hua Liu
Lin-Shan Bai
Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
Acta Crystallographica Section E
author_facet Zhu-Ping Xiao
Xin-Hua Liu
Lin-Shan Bai
author_sort Zhu-Ping Xiao
title Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
title_short Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
title_full Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
title_fullStr Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
title_full_unstemmed Tetrakis(μ-4-methylbenzoato-κO:O′)bis{[4-(dimethylamino)pyridine-κN1]zinc(II)}
title_sort tetrakis(μ-4-methylbenzoato-κo:o′)bis{[4-(dimethylamino)pyridine-κn1]zinc(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description In the centrosymmetric title binuclear complex, [Zn2(C8H7O2)4(C7H10N2)2], the Zn atoms [Zn...Zn = 3.0287 (6) Å] are bridged by four 4-methylbenzoate ligands. The four nearest O atoms around each ZnII atom form a distorted square-planar arrangement with the distorted square-pyramidal coordination completed by the pyridine N atom of the 4-(dimethylamino)pyridine ligand. In the crystal structure, weak intermolecular C—H...O interactions link the molecules into infinite chains. The chains are further linked by weak C—H...π interactions, forming a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809027603
work_keys_str_mv AT zhupingxiao tetrakisamp9564methylbenzoatoamp954ooamp8242bis4dimethylaminopyridineamp954n1zincii
AT xinhualiu tetrakisamp9564methylbenzoatoamp954ooamp8242bis4dimethylaminopyridineamp954n1zincii
AT linshanbai tetrakisamp9564methylbenzoatoamp954ooamp8242bis4dimethylaminopyridineamp954n1zincii
_version_ 1725815358011473920

Similar Items