catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S]
The title compound, [Mo2Zn(C3H5NO2S)2O2S2(H2O)2], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connec...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808007757 |
| id |
doaj-5842a8f33e864f3eb8b7efcd2fc93590 |
|---|---|
| record_format |
Article |
| spelling |
doaj-5842a8f33e864f3eb8b7efcd2fc935902020-11-25T00:50:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m605m60610.1107/S1600536808007757catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S]Genta SakaneShinobu OgasaharaTakashi ShibaharaThe title compound, [Mo2Zn(C3H5NO2S)2O2S2(H2O)2], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species.http://scripts.iucr.org/cgi-bin/paper?S1600536808007757 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Genta Sakane Shinobu Ogasahara Takashi Shibahara |
| spellingShingle |
Genta Sakane Shinobu Ogasahara Takashi Shibahara catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] Acta Crystallographica Section E |
| author_facet |
Genta Sakane Shinobu Ogasahara Takashi Shibahara |
| author_sort |
Genta Sakane |
| title |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] |
| title_short |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] |
| title_full |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] |
| title_fullStr |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] |
| title_full_unstemmed |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S] |
| title_sort |
catena-poly[[diaquazinc(ii)]-μ-l-cysteinato(2−)-κ4s:s,n,o-[di-μ-sulfido-bis[oxidomolybdate(v)](mo—mo)]-μ-l-cysteinato(2−)-κ4s,n,o:s] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-05-01 |
| description |
The title compound, [Mo2Zn(C3H5NO2S)2O2S2(H2O)2], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808007757 |
| work_keys_str_mv |
AT gentasakane catenapolydiaquazincii956lcysteinato287229544ssnodi956sulfidobisoxidomolybdatevmo8212mo956lcysteinato287229544snos AT shinobuogasahara catenapolydiaquazincii956lcysteinato287229544ssnodi956sulfidobisoxidomolybdatevmo8212mo956lcysteinato287229544snos AT takashishibahara catenapolydiaquazincii956lcysteinato287229544ssnodi956sulfidobisoxidomolybdatevmo8212mo956lcysteinato287229544snos |
| _version_ |
1725247456575225856 |