| Summary: | Supercritical operation is considered a main technique to achieve higher cycle efficiency in various thermodynamic systems. The present paper is a review of experimental investigations on supercritical operation considering both heat-to-upgraded heat and heat-to-power systems. Experimental works are reported and subsequently analyzed. Main findings can be summarized as: steam Rankine cycles does not show much studies in the literature, transcritical organic Rankine cycles are intensely investigated and few plants are already online, carbon dioxide is considered as a promising fluid for closed Brayton and Rankine cycles but its unique properties call for a new thinking in designing cycle components. Transcritical heat pumps are extensively used in domestic and industrial applications, but supercritical heat pumps with a working fluid other than CO<sub>2</sub> are scarce. To increase the adoption rate of supercritical thermodynamic systems further research is needed on the heat transfer behavior and the optimal design of compressors and expanders with special attention to the mechanical integrity.
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