1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine
The asymmetric unit of the title compound, C7H6ClN3S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)°...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812005442 |
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doaj-5a8505d090df4ae5bf456f62b766b5e52020-11-24T21:28:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o691o69210.1107/S16005368120054421-(6-Chloro-1,3-benzothiazol-2-yl)hydrazineB. NarayanaB. J. MohanB. K. SarojiniChin Wei OoiHoong-Kun FunThe asymmetric unit of the title compound, C7H6ClN3S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)° in molecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in molecule A and 172.50 (9) and −7.43 (13)°, respectively, in molecule B. In the crystal, neighbouring molecules are connected via pairs of N—H...N hydrogen bonds, generating R22(8) ring motifs, and are connected further by N—H...N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536812005442 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
B. Narayana B. J. Mohan B. K. Sarojini Chin Wei Ooi Hoong-Kun Fun |
| spellingShingle |
B. Narayana B. J. Mohan B. K. Sarojini Chin Wei Ooi Hoong-Kun Fun 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine Acta Crystallographica Section E |
| author_facet |
B. Narayana B. J. Mohan B. K. Sarojini Chin Wei Ooi Hoong-Kun Fun |
| author_sort |
B. Narayana |
| title |
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
| title_short |
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
| title_full |
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
| title_fullStr |
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
| title_full_unstemmed |
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
| title_sort |
1-(6-chloro-1,3-benzothiazol-2-yl)hydrazine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-03-01 |
| description |
The asymmetric unit of the title compound, C7H6ClN3S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)° in molecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in molecule A and 172.50 (9) and −7.43 (13)°, respectively, in molecule B. In the crystal, neighbouring molecules are connected via pairs of N—H...N hydrogen bonds, generating R22(8) ring motifs, and are connected further by N—H...N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3). |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812005442 |
| work_keys_str_mv |
AT bnarayana 16chloro13benzothiazol2ylhydrazine AT bjmohan 16chloro13benzothiazol2ylhydrazine AT bksarojini 16chloro13benzothiazol2ylhydrazine AT chinweiooi 16chloro13benzothiazol2ylhydrazine AT hoongkunfun 16chloro13benzothiazol2ylhydrazine |
| _version_ |
1725968260679073792 |