Investigation of the effect of organic solvents on kinetic parameters in metal catalyzed reactions

• Main Authors: Trifković Ljiljana, Milovanović Gordana A.
• Format: Article
• Language: English
• Published: Serbian Chemical Society 2000-01-01
• Series: Journal of the Serbian Chemical Society
• Subjects: kinetics; metal catalyzed reactions; acetone; acetonitrile; azorubin s; pyro-catechol violet; carminic acid; hydrogen peroxide
• Online Access: http://www.doiserbia.nb.rs/img/doi/0352-5139/2000/0352-51390003201T.pdf

The effects of acetone and acetonitrile on the kinetic parameters of azorubin S oxidation by hydrogen peroxide catalyzed by manganese(II), pyrocatechol violet oxidation by hydrogen peroxide catalyzed by copper(II), and carminic acid oxidation by hydrogen peroxide catalyzed by copper(II) and activated by bifenox, were examined. It was established that the examined solvents exhibit various effects on the kinetic parameters of the above said reactions. In all instances a change in the solvent concentration affects both the enthalpy and the entropy contributions to the free activation energy during the transition of the system into the active state, as well as the constant of the active complex formed at this point.