Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate
In the title mononuclear complex, [Zn(ClO4)(C17H11N3O)2]ClO4, the ZnII ion is coordinated in a distorted octahedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands i...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809025355 |
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doaj-5b9c736d478b49b88d7172e60038d5852020-11-25T01:56:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m882m88210.1107/S1600536809025355Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorateQing Ru ZhaoQi Sheng LiuQing Yun LiuIn the title mononuclear complex, [Zn(ClO4)(C17H11N3O)2]ClO4, the ZnII ion is coordinated in a distorted octahedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP ligand. Within the molecule there is a weak π–π interaction between the pyridine ring of the bidentate ligand and the 1,10-phenanthroline ring system of the tridendate ligand with a centroid–centroid distance of 3.6383 (19) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809025355 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Qing Ru Zhao Qi Sheng Liu Qing Yun Liu |
| spellingShingle |
Qing Ru Zhao Qi Sheng Liu Qing Yun Liu Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate Acta Crystallographica Section E |
| author_facet |
Qing Ru Zhao Qi Sheng Liu Qing Yun Liu |
| author_sort |
Qing Ru Zhao |
| title |
Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate |
| title_short |
Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate |
| title_full |
Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate |
| title_fullStr |
Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate |
| title_full_unstemmed |
Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate |
| title_sort |
perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(ii) perchlorate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-08-01 |
| description |
In the title mononuclear complex, [Zn(ClO4)(C17H11N3O)2]ClO4, the ZnII ion is coordinated in a distorted octahedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP ligand. Within the molecule there is a weak π–π interaction between the pyridine ring of the bidentate ligand and the 1,10-phenanthroline ring system of the tridendate ligand with a centroid–centroid distance of 3.6383 (19) Å. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809025355 |
| work_keys_str_mv |
AT qingruzhao perchloratobis1110phenanthrolin2yl2pyridonezinciiperchlorate AT qishengliu perchloratobis1110phenanthrolin2yl2pyridonezinciiperchlorate AT qingyunliu perchloratobis1110phenanthrolin2yl2pyridonezinciiperchlorate |
| _version_ |
1724978802319163392 |