Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy
Enriched boron-10 and its related compounds have great application prospects, especially in the nuclear industry. The chemical exchange rectification method is one of the most important ways to separate the <sup>10</sup>B and <sup>11</sup>B isotope. However, a real-time monit...
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doaj-5c0167973206459c96f93a232aea7d692020-11-25T01:06:33ZengMDPI AGApplied Sciences2076-34172018-12-01812250910.3390/app8122509app8122509Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared SpectroscopyWeijiang Zhang0Yin Tang1Jiao Xu2School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, ChinaEnriched boron-10 and its related compounds have great application prospects, especially in the nuclear industry. The chemical exchange rectification method is one of the most important ways to separate the <sup>10</sup>B and <sup>11</sup>B isotope. However, a real-time monitoring method is needed because this separation process is difficult to characterize. Infrared spectroscopy was applied in the separation device to realize the online determination of the boron isotope ratio in boron trifluoride (BF<sub>3</sub>). The possibility of determining the isotope ratio via the 2ν<sub>3</sub> band was explored. A correction factor was introduced to eliminate the difference between the ratio of peak areas and the true value of the boron isotope ratio. It was experimentally found that the influences of pressure and temperature could be ignored. The results showed that the infrared method has enough precision and stability for real-time, in situ determination of the boron isotope ratio. The instability point of the isotope ratio can be detected with the assistance of the online determination method and provides a reference for the production of boron isotope.https://www.mdpi.com/2076-3417/8/12/2509isotopeboroninfrared spectroscopyonline determination |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Weijiang Zhang Yin Tang Jiao Xu |
spellingShingle |
Weijiang Zhang Yin Tang Jiao Xu Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy Applied Sciences isotope boron infrared spectroscopy online determination |
author_facet |
Weijiang Zhang Yin Tang Jiao Xu |
author_sort |
Weijiang Zhang |
title |
Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy |
title_short |
Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy |
title_full |
Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy |
title_fullStr |
Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy |
title_full_unstemmed |
Online Determination of Boron Isotope Ratio in Boron Trifluoride by Infrared Spectroscopy |
title_sort |
online determination of boron isotope ratio in boron trifluoride by infrared spectroscopy |
publisher |
MDPI AG |
series |
Applied Sciences |
issn |
2076-3417 |
publishDate |
2018-12-01 |
description |
Enriched boron-10 and its related compounds have great application prospects, especially in the nuclear industry. The chemical exchange rectification method is one of the most important ways to separate the <sup>10</sup>B and <sup>11</sup>B isotope. However, a real-time monitoring method is needed because this separation process is difficult to characterize. Infrared spectroscopy was applied in the separation device to realize the online determination of the boron isotope ratio in boron trifluoride (BF<sub>3</sub>). The possibility of determining the isotope ratio via the 2ν<sub>3</sub> band was explored. A correction factor was introduced to eliminate the difference between the ratio of peak areas and the true value of the boron isotope ratio. It was experimentally found that the influences of pressure and temperature could be ignored. The results showed that the infrared method has enough precision and stability for real-time, in situ determination of the boron isotope ratio. The instability point of the isotope ratio can be detected with the assistance of the online determination method and provides a reference for the production of boron isotope. |
topic |
isotope boron infrared spectroscopy online determination |
url |
https://www.mdpi.com/2076-3417/8/12/2509 |
work_keys_str_mv |
AT weijiangzhang onlinedeterminationofboronisotoperatioinborontrifluoridebyinfraredspectroscopy AT yintang onlinedeterminationofboronisotoperatioinborontrifluoridebyinfraredspectroscopy AT jiaoxu onlinedeterminationofboronisotoperatioinborontrifluoridebyinfraredspectroscopy |
_version_ |
1725189609647767552 |