Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride

Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride

The cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine...

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Main Authors: Neelakandan Devika, Nandhagopal Raja, Subbiah Ananthalakshmi, Bruno Therrien
Format: Article
Language:English
Published: International Union of Crystallography 2015-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
rhodium(III) complex
pentamethylcyclopentadienyl
piano-stool geometry
N—H...Cl hydrogen bond
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901500184X
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spelling doaj-5cdd99962dc44bca806cd9d8bdf2f8bf2020-11-24T21:46:35ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-03-0171324825010.1107/S205698901500184Xrz5146Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chlorideNeelakandan Devika0Nandhagopal Raja1Subbiah Ananthalakshmi2Bruno Therrien3Department of Chemistry, BIT Campus, Anna University, Tiruchirappalli 620 024, Tamil Nadu State, IndiaInstitut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, SwitzerlandDepartment of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620 019, Tamil Nadu State, IndiaInstitut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, SwitzerlandThe cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chlorophenyl)hydrazin-1-ylidene]ethyl group. In the crystal, a weak interionic N—H...Cl hydrogen bond is observed.http://scripts.iucr.org/cgi-bin/paper?S205698901500184Xcrystal structurerhodium(III) complexpentamethylcyclopentadienylpiano-stool geometryN—H...Cl hydrogen bond
collection DOAJ
language English
format Article
sources DOAJ
author Neelakandan Devika
Nandhagopal Raja
Subbiah Ananthalakshmi
Bruno Therrien
spellingShingle Neelakandan Devika
Nandhagopal Raja
Subbiah Ananthalakshmi
Bruno Therrien
Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
rhodium(III) complex
pentamethylcyclopentadienyl
piano-stool geometry
N—H...Cl hydrogen bond
author_facet Neelakandan Devika
Nandhagopal Raja
Subbiah Ananthalakshmi
Bruno Therrien
author_sort Neelakandan Devika
title Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
title_short Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
title_full Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
title_fullStr Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
title_full_unstemmed Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride
title_sort crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κn]ethyl}pyridine-κn)(η5-pentamethylcyclopentadienyl)rhodium(iii) chloride
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-03-01
description The cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chlorophenyl)hydrazin-1-ylidene]ethyl group. In the crystal, a weak interionic N—H...Cl hydrogen bond is observed.
topic crystal structure
rhodium(III) complex
pentamethylcyclopentadienyl
piano-stool geometry
N—H...Cl hydrogen bond
url http://scripts.iucr.org/cgi-bin/paper?S205698901500184X
work_keys_str_mv AT neelakandandevika crystalstructureofchlorido2124chlorophenylhydrazin1ylideneknethylpyridineknē5pentamethylcyclopentadienylrhodiumiiichloride
AT nandhagopalraja crystalstructureofchlorido2124chlorophenylhydrazin1ylideneknethylpyridineknē5pentamethylcyclopentadienylrhodiumiiichloride
AT subbiahananthalakshmi crystalstructureofchlorido2124chlorophenylhydrazin1ylideneknethylpyridineknē5pentamethylcyclopentadienylrhodiumiiichloride
AT brunotherrien crystalstructureofchlorido2124chlorophenylhydrazin1ylideneknethylpyridineknē5pentamethylcyclopentadienylrhodiumiiichloride
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