Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]]
In the title compound {(C3H5N2)[Na(NO3)2]}n, the NaI ion is coordinated by eight O atoms from three bidentate nitrate anions and two O atoms from two monodentate nitrate anions, displaying a bicapped trigonal–prismatic geometry. The imidazolium cation is essentially planar (r.m.s. deviatio...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2013-06-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813011951 |
id |
doaj-5dc301a08f644bf69f9ada2307bda1d8 |
---|---|
record_format |
Article |
spelling |
doaj-5dc301a08f644bf69f9ada2307bda1d82020-11-24T21:30:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696m303m30410.1107/S1600536813011951Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]]Chahrazed TrifaAmira BouhaliSofiane BouacidaChaouki BoudarenThierry BatailleIn the title compound {(C3H5N2)[Na(NO3)2]}n, the NaI ion is coordinated by eight O atoms from three bidentate nitrate anions and two O atoms from two monodentate nitrate anions, displaying a bicapped trigonal–prismatic geometry. The imidazolium cation is essentially planar (r.m.s. deviation for all non-H atoms = 0.0018 Å). In the crystal, the NaI ions are connected by bridging nitrate ligands, forming layers parallel to (010). The imidazolium cations are sandwiched between these layers. Weak C—H...O hydrogen bonds link the layers into a three-dimensional network. In addtion, π–π interactions between the imidazolium rings [centroid–centroid distance = 3.588 (3) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536813011951 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Chahrazed Trifa Amira Bouhali Sofiane Bouacida Chaouki Boudaren Thierry Bataille |
spellingShingle |
Chahrazed Trifa Amira Bouhali Sofiane Bouacida Chaouki Boudaren Thierry Bataille Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] Acta Crystallographica Section E |
author_facet |
Chahrazed Trifa Amira Bouhali Sofiane Bouacida Chaouki Boudaren Thierry Bataille |
author_sort |
Chahrazed Trifa |
title |
Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] |
title_short |
Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] |
title_full |
Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] |
title_fullStr |
Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] |
title_full_unstemmed |
Poly[1H-imidazol-3-ium [di-μ-nitrato-sodium]] |
title_sort |
poly[1h-imidazol-3-ium [di-μ-nitrato-sodium]] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2013-06-01 |
description |
In the title compound {(C3H5N2)[Na(NO3)2]}n, the NaI ion is coordinated by eight O atoms from three bidentate nitrate anions and two O atoms from two monodentate nitrate anions, displaying a bicapped trigonal–prismatic geometry. The imidazolium cation is essentially planar (r.m.s. deviation for all non-H atoms = 0.0018 Å). In the crystal, the NaI ions are connected by bridging nitrate ligands, forming layers parallel to (010). The imidazolium cations are sandwiched between these layers. Weak C—H...O hydrogen bonds link the layers into a three-dimensional network. In addtion, π–π interactions between the imidazolium rings [centroid–centroid distance = 3.588 (3) Å] are observed. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813011951 |
work_keys_str_mv |
AT chahrazedtrifa poly1himidazol3iumdi956nitratosodium AT amirabouhali poly1himidazol3iumdi956nitratosodium AT sofianebouacida poly1himidazol3iumdi956nitratosodium AT chaoukiboudaren poly1himidazol3iumdi956nitratosodium AT thierrybataille poly1himidazol3iumdi956nitratosodium |
_version_ |
1725962588331704320 |