catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O ato...
Main Author: | |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-11-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810039711 |
Summary: | The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O atoms from two carboxylate groups and two water O atoms. An intramolecular C—H...O hydrogen bond occurs. In the crystal, intermolecular hydrogen bonds between carboxylate O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure. The compound is isotypic with the Zn analog. |
---|---|
ISSN: | 1600-5368 |