catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]

catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]

The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O ato...

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Main Author: Chang-mei Jiao
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810039711
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spelling doaj-5dc8d57116b84241ba15b01704e836702020-11-25T02:46:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1405m140510.1107/S1600536810039711catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]Chang-mei JiaoThe title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O atoms from two carboxylate groups and two water O atoms. An intramolecular C—H...O hydrogen bond occurs. In the crystal, intermolecular hydrogen bonds between carboxylate O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure. The compound is isotypic with the Zn analog. http://scripts.iucr.org/cgi-bin/paper?S1600536810039711
collection DOAJ
language English
format Article
sources DOAJ
author Chang-mei Jiao
spellingShingle Chang-mei Jiao
catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
Acta Crystallographica Section E
author_facet Chang-mei Jiao
author_sort Chang-mei Jiao
title catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
title_short catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
title_full catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
title_fullStr catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
title_full_unstemmed catena-Poly[[diaquacadmium(II)]-μ-4,4′-sulfonyldibenzoato-κ2O1:O1′]
title_sort catena-poly[[diaquacadmium(ii)]-μ-4,4′-sulfonyldibenzoato-κ2o1:o1′]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O atoms from two carboxylate groups and two water O atoms. An intramolecular C—H...O hydrogen bond occurs. In the crystal, intermolecular hydrogen bonds between carboxylate O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure. The compound is isotypic with the Zn analog.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810039711
work_keys_str_mv AT changmeijiao catenapolydiaquacadmiumiiamp95644amp8242sulfonyldibenzoatoamp9542o1o1amp8242
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