<b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>

<b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>

New Hofmann type clathrates in the form of M(4-Phpy) <sub>2</sub>Ni(CN) <sub>4</sub>.2G (where 4-Phpy = 4-phenylpyridine, G = 1,4-dioxane and M = Ni, Co and Cd) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that th...

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Main Author: Cemal Parlak
Format: Article
Language:English
Published: Chemical Society of Ethiopia 2010-06-01
Series:Bulletin of the Chemical Society of Ethiopia
Subjects:
Hofmann type clathrates
Vibrational spectra
4-Phenylpyridine
1
4-Dioxane
Online Access:http://ajol.info/index.php/bcse/article/view/60679
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spelling doaj-5ddbaef9bb3c45ee88427529b8cce8472020-11-24T21:12:01ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2010-06-01243375381<b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>Cemal ParlakNew Hofmann type clathrates in the form of M(4-Phpy) <sub>2</sub>Ni(CN) <sub>4</sub>.2G (where 4-Phpy = 4-phenylpyridine, G = 1,4-dioxane and M = Ni, Co and Cd) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann type clathrates and their structures consist of polymeric layers of |M-Ni(CN) <sub>4</sub>|∞ with the 4-Phpy bound to the metal (M) atom.http://ajol.info/index.php/bcse/article/view/60679Hofmann type clathratesVibrational spectra4-Phenylpyridine14-Dioxane
collection DOAJ
language English
format Article
sources DOAJ
author Cemal Parlak
spellingShingle Cemal Parlak
<b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
Bulletin of the Chemical Society of Ethiopia
Hofmann type clathrates
Vibrational spectra
4-Phenylpyridine
1
4-Dioxane
author_facet Cemal Parlak
author_sort Cemal Parlak
title <b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
title_short <b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
title_full <b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
title_fullStr <b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
title_full_unstemmed <b>Vibrational spectroscopic investigation of some Hofmann type clathrates: M(4-phenylpyridine)<sub>2</sub>Ni(CN)<sub>4</sub>.2G (M = Ni, Co and Cd, G = 1,4-dioxane)</b>
title_sort <b>vibrational spectroscopic investigation of some hofmann type clathrates: m(4-phenylpyridine)<sub>2</sub>ni(cn)<sub>4</sub>.2g (m = ni, co and cd, g = 1,4-dioxane)</b>
publisher Chemical Society of Ethiopia
series Bulletin of the Chemical Society of Ethiopia
issn 1011-3924
1726-801X
publishDate 2010-06-01
description New Hofmann type clathrates in the form of M(4-Phpy) <sub>2</sub>Ni(CN) <sub>4</sub>.2G (where 4-Phpy = 4-phenylpyridine, G = 1,4-dioxane and M = Ni, Co and Cd) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann type clathrates and their structures consist of polymeric layers of |M-Ni(CN) <sub>4</sub>|∞ with the 4-Phpy bound to the metal (M) atom.
topic Hofmann type clathrates
Vibrational spectra
4-Phenylpyridine
1
4-Dioxane
url http://ajol.info/index.php/bcse/article/view/60679
work_keys_str_mv AT cemalparlak bvibrationalspectroscopicinvestigationofsomehofmanntypeclathratesm4phenylpyridinesub2subnicnsub4sub2gmnicoandcdg14dioxaneb
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