Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite

Pyrite is a common mineral with a higher density than most other minerals in the Eagle Ford Shale formation. Hence, if pyrite is not considered in the total organic carbon (TOC) estimation, based on density logs, it may lead to errors. In order to improve the accuracy of the TOC estimation, we propo...

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Main Authors: Shuxian Jiang, Mehdi Mokhtari, David Borrok, Jim Lee
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Minerals
Subjects:
TOC
Online Access:http://www.mdpi.com/2075-163X/8/4/154
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spelling doaj-5f31498be1c440c0891ba400b3b9abcc2020-11-25T00:59:51ZengMDPI AGMinerals2075-163X2018-04-018415410.3390/min8040154min8040154Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of PyriteShuxian Jiang0Mehdi Mokhtari1David Borrok2Jim Lee3Department of Petroleum Engineering, University of Louisiana at Lafayette, Lafayette, LA 70504, USADepartment of Petroleum Engineering, University of Louisiana at Lafayette, Lafayette, LA 70504, USADepartment of Geosciences and Geological and Petroleum Engineering, Missouri University of Science and Technology, Rolla, MO 65409, USADepartment of Mechanical Engineering, University of Louisiana at Lafayette, Lafayette, LA 70504, USAPyrite is a common mineral with a higher density than most other minerals in the Eagle Ford Shale formation. Hence, if pyrite is not considered in the total organic carbon (TOC) estimation, based on density logs, it may lead to errors. In order to improve the accuracy of the TOC estimation, we propose an updated TOC estimation method that incorporates the concentration of pyrite and organic porosity. More than 15 m of Eagle Ford Shale samples were analyzed using Rock-Eval pyrolysis, X-ray fluorescence (XRF), and X-ray diffraction (XRD). TOC, elemental concentration, and mineralogical data were analyzed for a better understanding of the relationship between the concentration of TOC and pyrite content in the Eagle Ford formation. An updated petrophysical model—including parameters such as organic pores, solid organic matter, inorganic pores, pyrite, and inorganic rock matrix without pyrite—was built using the sample data from the Eagle Ford. The model was compared with Schmoker’s model and validated with the Eagle Ford field data. The results showed that the updated model had a lower root mean square error (RMSE) than Schmoker’s model. Therefore, it could be used in the future estimation of TOC in pyrite-rich formations.http://www.mdpi.com/2075-163X/8/4/154TOCEagle Ford Shalepyritedensity log
collection DOAJ
language English
format Article
sources DOAJ
author Shuxian Jiang
Mehdi Mokhtari
David Borrok
Jim Lee
spellingShingle Shuxian Jiang
Mehdi Mokhtari
David Borrok
Jim Lee
Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
Minerals
TOC
Eagle Ford Shale
pyrite
density log
author_facet Shuxian Jiang
Mehdi Mokhtari
David Borrok
Jim Lee
author_sort Shuxian Jiang
title Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
title_short Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
title_full Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
title_fullStr Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
title_full_unstemmed Improving the Total Organic Carbon Estimation of the Eagle Ford Shale with Density Logs by Considering the Effect of Pyrite
title_sort improving the total organic carbon estimation of the eagle ford shale with density logs by considering the effect of pyrite
publisher MDPI AG
series Minerals
issn 2075-163X
publishDate 2018-04-01
description Pyrite is a common mineral with a higher density than most other minerals in the Eagle Ford Shale formation. Hence, if pyrite is not considered in the total organic carbon (TOC) estimation, based on density logs, it may lead to errors. In order to improve the accuracy of the TOC estimation, we propose an updated TOC estimation method that incorporates the concentration of pyrite and organic porosity. More than 15 m of Eagle Ford Shale samples were analyzed using Rock-Eval pyrolysis, X-ray fluorescence (XRF), and X-ray diffraction (XRD). TOC, elemental concentration, and mineralogical data were analyzed for a better understanding of the relationship between the concentration of TOC and pyrite content in the Eagle Ford formation. An updated petrophysical model—including parameters such as organic pores, solid organic matter, inorganic pores, pyrite, and inorganic rock matrix without pyrite—was built using the sample data from the Eagle Ford. The model was compared with Schmoker’s model and validated with the Eagle Ford field data. The results showed that the updated model had a lower root mean square error (RMSE) than Schmoker’s model. Therefore, it could be used in the future estimation of TOC in pyrite-rich formations.
topic TOC
Eagle Ford Shale
pyrite
density log
url http://www.mdpi.com/2075-163X/8/4/154
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AT davidborrok improvingthetotalorganiccarbonestimationoftheeaglefordshalewithdensitylogsbyconsideringtheeffectofpyrite
AT jimlee improvingthetotalorganiccarbonestimationoftheeaglefordshalewithdensitylogsbyconsideringtheeffectofpyrite
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