{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)

{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)

The asymmetric unit of the title compound, [Co(C23H28N2O4)(C9H9O3)]·C2H5OH·H2O, comprises one complex molecule, a water molecule of crystallization and an ethanol molecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of...

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Main Authors: Reza Kia, Hadi Kargar, Karim Zare, Islam Ullah Khan
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810007622
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spelling doaj-5f638c21d6ca49d3a7e0943a93f031f02020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m366m36710.1107/S1600536810007622{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)Reza KiaHadi KargarKarim ZareIslam Ullah KhanThe asymmetric unit of the title compound, [Co(C23H28N2O4)(C9H9O3)]·C2H5OH·H2O, comprises one complex molecule, a water molecule of crystallization and an ethanol molecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0.567 (10):0.433 (10). The CoIII ion is in a slightly distorted octahedral geometry involving an N2O2 atom set of the tetradenate Schiff base ligand and two O atoms of 2-ethoxy-6-formylphenolate. The H atoms of the water molecule act as donors in the formation of bifurcated intermolecular O—H...(O,O) hydrogen bonds with the O atoms of the hydroxy and ethoxy groups with R12(5) ring motifs, which may influence the molecular conformation. The crystal structure is further stabilized by intermolecular O—H...O and C—H...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810007622
collection DOAJ
language English
format Article
sources DOAJ
author Reza Kia
Hadi Kargar
Karim Zare
Islam Ullah Khan
spellingShingle Reza Kia
Hadi Kargar
Karim Zare
Islam Ullah Khan
{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
Acta Crystallographica Section E
author_facet Reza Kia
Hadi Kargar
Karim Zare
Islam Ullah Khan
author_sort Reza Kia
title {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
title_short {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
title_full {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
title_fullStr {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
title_full_unstemmed {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
title_sort {6,6′-diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(iii)–ethanol–water (1/1/1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description The asymmetric unit of the title compound, [Co(C23H28N2O4)(C9H9O3)]·C2H5OH·H2O, comprises one complex molecule, a water molecule of crystallization and an ethanol molecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0.567 (10):0.433 (10). The CoIII ion is in a slightly distorted octahedral geometry involving an N2O2 atom set of the tetradenate Schiff base ligand and two O atoms of 2-ethoxy-6-formylphenolate. The H atoms of the water molecule act as donors in the formation of bifurcated intermolecular O—H...(O,O) hydrogen bonds with the O atoms of the hydroxy and ethoxy groups with R12(5) ring motifs, which may influence the molecular conformation. The crystal structure is further stabilized by intermolecular O—H...O and C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810007622
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AT hadikargar 66amp8242diethoxy22amp824222dimethylpropane13diylbisnitrilomethylidynediphenolato2ethoxy6formylphenolatocobaltiiiamp8211ethanolamp8211water111
AT karimzare 66amp8242diethoxy22amp824222dimethylpropane13diylbisnitrilomethylidynediphenolato2ethoxy6formylphenolatocobaltiiiamp8211ethanolamp8211water111
AT islamullahkhan 66amp8242diethoxy22amp824222dimethylpropane13diylbisnitrilomethylidynediphenolato2ethoxy6formylphenolatocobaltiiiamp8211ethanolamp8211water111
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