Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate

Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate

In the title compound, [Ni(C6H6N4)2(H2O)2](C8H7O2)2·2C8H8O2, the NiII atom (site symmetry overline{1}) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two water molecules, resulting in a slightly distorted trans-NiO2N4 geometry for the metal...

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Main Author: Zhou Hui
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809044705
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spelling doaj-60647bde3cb64691be60a31e05e067342020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1497m149710.1107/S1600536809044705Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvateZhou HuiIn the title compound, [Ni(C6H6N4)2(H2O)2](C8H7O2)2·2C8H8O2, the NiII atom (site symmetry overline{1}) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two water molecules, resulting in a slightly distorted trans-NiO2N4 geometry for the metal ion. In the crystal, the components are linked by N—H...O and O—H...O hydrogen bonds, generating an infinite two-dimensional network running parallel to (100). The methyl group of the benzoic acid molecule is disordered over two sites in a 0.563 (17):0.437 (17) ratio. http://scripts.iucr.org/cgi-bin/paper?S1600536809044705
collection DOAJ
language English
format Article
sources DOAJ
author Zhou Hui
spellingShingle Zhou Hui
Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
Acta Crystallographica Section E
author_facet Zhou Hui
author_sort Zhou Hui
title Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
title_short Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
title_full Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
title_fullStr Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
title_full_unstemmed Diaquabis(2,2′-bi-1H-imidazole-κ2N3,N3′)nickel(II) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
title_sort diaquabis(2,2′-bi-1h-imidazole-κ2n3,n3′)nickel(ii) bis(3-methylbenzoate) 3-methylbenzoic acid disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description In the title compound, [Ni(C6H6N4)2(H2O)2](C8H7O2)2·2C8H8O2, the NiII atom (site symmetry overline{1}) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two water molecules, resulting in a slightly distorted trans-NiO2N4 geometry for the metal ion. In the crystal, the components are linked by N—H...O and O—H...O hydrogen bonds, generating an infinite two-dimensional network running parallel to (100). The methyl group of the benzoic acid molecule is disordered over two sites in a 0.563 (17):0.437 (17) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809044705
work_keys_str_mv AT zhouhui diaquabis22amp8242bi1himidazoleamp9542n3n3amp8242nickeliibis3methylbenzoate3methylbenzoicaciddisolvate
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