Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate

In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)...

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Main Authors:	Igor Elkin, Thierry Maris, Alexandre Melkoumov, Patrice Hildgen, Xavier Banquy, Grégoire Leclair, Christopher Barrett
Format:	Article
Language:	English
Published:	International Union of Crystallography 2018-04-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure azobenzene 2-pyrrolidone cyclic γ-aminobutyric acid derivative GABA racetam
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S205698901800333X

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spelling	doaj-608e8eeb68824de3aabe911a44c7882e2020-11-24T22:20:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-04-0174445846010.1107/S205698901800333Xff2152Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoateIgor Elkin0Thierry Maris1Alexandre Melkoumov2Patrice Hildgen3Xavier Banquy4Grégoire Leclair5Christopher Barrett6Otto Maass Chemistry Building, Office 430, Chemistry Department, McGill University, 801 Sherbrooke St. W., Montreal, Quebec, Canada, H3A 0B8Department of Chemistry, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Otto Maass Chemistry Building, Office 430, Chemistry Department, McGill University, 801 Sherbrooke St. W., Montreal, Quebec, Canada, H3A 0B8In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking interactions, forming zigzag supramolecular chains parallel to [010] further linked via additional C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S205698901800333Xcrystal structureazobenzene2-pyrrolidonecyclic γ-aminobutyric acid derivativeGABAracetam
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett
spellingShingle	Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate Acta Crystallographica Section E: Crystallographic Communications crystal structure azobenzene 2-pyrrolidone cyclic γ-aminobutyric acid derivative GABA racetam
author_facet	Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett
author_sort	Igor Elkin
title	Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
title_short	Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
title_full	Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
title_fullStr	Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
title_full_unstemmed	Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
title_sort	crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2018-04-01
description	In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking interactions, forming zigzag supramolecular chains parallel to [010] further linked via additional C—H...π interactions.
topic	crystal structure azobenzene 2-pyrrolidone cyclic γ-aminobutyric acid derivative GABA racetam
url	http://scripts.iucr.org/cgi-bin/paper?S205698901800333X
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Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate

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