Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate
In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2018-04-01
|
Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698901800333X |
id |
doaj-608e8eeb68824de3aabe911a44c7882e |
---|---|
record_format |
Article |
spelling |
doaj-608e8eeb68824de3aabe911a44c7882e2020-11-24T22:20:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-04-0174445846010.1107/S205698901800333Xff2152Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoateIgor Elkin0Thierry Maris1Alexandre Melkoumov2Patrice Hildgen3Xavier Banquy4Grégoire Leclair5Christopher Barrett6Otto Maass Chemistry Building, Office 430, Chemistry Department, McGill University, 801 Sherbrooke St. W., Montreal, Quebec, Canada, H3A 0B8Department of Chemistry, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Faculty of Pharmacy, Université de Montréal, 2900 Edouard-Montpetit Blvd., Montreal, Quebec, Canada, H3C 3J7Otto Maass Chemistry Building, Office 430, Chemistry Department, McGill University, 801 Sherbrooke St. W., Montreal, Quebec, Canada, H3A 0B8In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking interactions, forming zigzag supramolecular chains parallel to [010] further linked via additional C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S205698901800333Xcrystal structureazobenzene2-pyrrolidonecyclic γ-aminobutyric acid derivativeGABAracetam |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett |
spellingShingle |
Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate Acta Crystallographica Section E: Crystallographic Communications crystal structure azobenzene 2-pyrrolidone cyclic γ-aminobutyric acid derivative GABA racetam |
author_facet |
Igor Elkin Thierry Maris Alexandre Melkoumov Patrice Hildgen Xavier Banquy Grégoire Leclair Christopher Barrett |
author_sort |
Igor Elkin |
title |
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
title_short |
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
title_full |
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
title_fullStr |
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
title_full_unstemmed |
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
title_sort |
crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyldiazen-1-yl)benzoate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2018-04-01 |
description |
In the title compound, C17H15N3O3, the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azobenzene segment, which adopts a configuration close to planar. In the crystal, molecules are oriented pairwise by (2-oxopyrrolidin-3-yl)oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking interactions, forming zigzag supramolecular chains parallel to [010] further linked via additional C—H...π interactions. |
topic |
crystal structure azobenzene 2-pyrrolidone cyclic γ-aminobutyric acid derivative GABA racetam |
url |
http://scripts.iucr.org/cgi-bin/paper?S205698901800333X |
work_keys_str_mv |
AT igorelkin crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT thierrymaris crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT alexandremelkoumov crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT patricehildgen crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT xavierbanquy crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT gregoireleclair crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate AT christopherbarrett crystalstructureof2oxopyrrolidin3yl42phenyldiazen1ylbenzoate |
_version_ |
1725773226665050112 |