Dichlorido{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethylformamide solvate
In the heterodinuclear complex of the title compound, [PbZn(C22H18N2O4)Cl2(C2H6OS)]·C3H7NO, the ZnII atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The PbII atom is...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808034338 |
| Summary: | In the heterodinuclear complex of the title compound, [PbZn(C22H18N2O4)Cl2(C2H6OS)]·C3H7NO, the ZnII atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The PbII atom is coordinated in a distorted octahedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide molecule and one Cl atom. The dimethyl sulfoxide molecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2). |
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| ISSN: | 1600-5368 |