Synthesis of sodium polyhydrides at high pressures

The only known compound of sodium and hydrogen is ionic NaH, but theory predicts the existence of polyhydrides at high pressure. Here, the authors report observations of the formation of polyhydrides above 40 GPa and 2000 K, supporting the idea of multicentre bonding in a material with unusual stoic...

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Main Authors: Viktor V. Struzhkin, Duck Young Kim, Elissaios Stavrou, Takaki Muramatsu, Ho-kwang Mao, Chris J. Pickard, Richard J. Needs, Vitali B. Prakapenka, Alexander F. Goncharov
Format: Article
Language:English
Published: Nature Publishing Group 2016-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms12267
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spelling doaj-62e8260d819343079037f36b20abd4bf2021-05-11T10:52:09ZengNature Publishing GroupNature Communications2041-17232016-07-01711810.1038/ncomms12267Synthesis of sodium polyhydrides at high pressuresViktor V. Struzhkin0Duck Young Kim1Elissaios Stavrou2Takaki Muramatsu3Ho-kwang Mao4Chris J. Pickard5Richard J. Needs6Vitali B. Prakapenka7Alexander F. Goncharov8Geophysical Laboratory, Carnegie Institution of WashingtonGeophysical Laboratory, Carnegie Institution of WashingtonGeophysical Laboratory, Carnegie Institution of WashingtonGeophysical Laboratory, Carnegie Institution of WashingtonGeophysical Laboratory, Carnegie Institution of WashingtonDepartment of Physics and Astronomy, University College LondonTheory of Condensed Matter Group, Cavendish LaboratoryCenter for Advanced Radiation Sources, The University of ChicagoGeophysical Laboratory, Carnegie Institution of WashingtonThe only known compound of sodium and hydrogen is ionic NaH, but theory predicts the existence of polyhydrides at high pressure. Here, the authors report observations of the formation of polyhydrides above 40 GPa and 2000 K, supporting the idea of multicentre bonding in a material with unusual stoichiometry.https://doi.org/10.1038/ncomms12267
collection DOAJ
language English
format Article
sources DOAJ
author Viktor V. Struzhkin
Duck Young Kim
Elissaios Stavrou
Takaki Muramatsu
Ho-kwang Mao
Chris J. Pickard
Richard J. Needs
Vitali B. Prakapenka
Alexander F. Goncharov
spellingShingle Viktor V. Struzhkin
Duck Young Kim
Elissaios Stavrou
Takaki Muramatsu
Ho-kwang Mao
Chris J. Pickard
Richard J. Needs
Vitali B. Prakapenka
Alexander F. Goncharov
Synthesis of sodium polyhydrides at high pressures
Nature Communications
author_facet Viktor V. Struzhkin
Duck Young Kim
Elissaios Stavrou
Takaki Muramatsu
Ho-kwang Mao
Chris J. Pickard
Richard J. Needs
Vitali B. Prakapenka
Alexander F. Goncharov
author_sort Viktor V. Struzhkin
title Synthesis of sodium polyhydrides at high pressures
title_short Synthesis of sodium polyhydrides at high pressures
title_full Synthesis of sodium polyhydrides at high pressures
title_fullStr Synthesis of sodium polyhydrides at high pressures
title_full_unstemmed Synthesis of sodium polyhydrides at high pressures
title_sort synthesis of sodium polyhydrides at high pressures
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2016-07-01
description The only known compound of sodium and hydrogen is ionic NaH, but theory predicts the existence of polyhydrides at high pressure. Here, the authors report observations of the formation of polyhydrides above 40 GPa and 2000 K, supporting the idea of multicentre bonding in a material with unusual stoichiometry.
url https://doi.org/10.1038/ncomms12267
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