Novel 24-membered octanuclear manganese(III) metallacrown
A novel octanuclear manganese metalladiazamacrocycle (1) was synthesized employing a new pentadentate ligand N-methacryl-5-methylsalicylhydrazide (H3mamshz) by supramolecular self assembly. The backbone of this metal-organic assembly is a repeating unit of Mn–N–N–Mn linkage that extends to complete...
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Chemical Society of Ethiopia
2014-09-01
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| Series: | Bulletin of the Chemical Society of Ethiopia |
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| Online Access: | http://www.ajol.info/index.php/bcse/article/view/108084 |
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doaj-63083393b7214dfc938d5e6df5b8983f2020-11-24T23:18:37ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2014-09-01283403408http://dx.doi.org/10.4314/bcse.v28i3.9Novel 24-membered octanuclear manganese(III) metallacrownF. DangD. ZhaoH. Guo K. W. LeiA novel octanuclear manganese metalladiazamacrocycle (1) was synthesized employing a new pentadentate ligand N-methacryl-5-methylsalicylhydrazide (H3mamshz) by supramolecular self assembly. The backbone of this metal-organic assembly is a repeating unit of Mn–N–N–Mn linkage that extends to complete a 24-membered cyclic structure involving 8 manganese(III) centers. Successive manganese centers are in an octanuclear cyclic structure. The temperature-dependent magnetic properties show a typical weakly coupled antiferromagnetic behaviour. DOI: http://dx.doi.org/10.4314/bcse.v28i3.9http://www.ajol.info/index.php/bcse/article/view/108084ManganeseOctanuclearMetalladiazamacrocyclePentadentate ligandAntiferromagnetic behavior |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
F. Dang D. Zhao H. Guo K. W. Lei |
| spellingShingle |
F. Dang D. Zhao H. Guo K. W. Lei Novel 24-membered octanuclear manganese(III) metallacrown Bulletin of the Chemical Society of Ethiopia Manganese Octanuclear Metalladiazamacrocycle Pentadentate ligand Antiferromagnetic behavior |
| author_facet |
F. Dang D. Zhao H. Guo K. W. Lei |
| author_sort |
F. Dang |
| title |
Novel 24-membered octanuclear manganese(III) metallacrown |
| title_short |
Novel 24-membered octanuclear manganese(III) metallacrown |
| title_full |
Novel 24-membered octanuclear manganese(III) metallacrown |
| title_fullStr |
Novel 24-membered octanuclear manganese(III) metallacrown |
| title_full_unstemmed |
Novel 24-membered octanuclear manganese(III) metallacrown |
| title_sort |
novel 24-membered octanuclear manganese(iii) metallacrown |
| publisher |
Chemical Society of Ethiopia |
| series |
Bulletin of the Chemical Society of Ethiopia |
| issn |
1011-3924 1726-801X |
| publishDate |
2014-09-01 |
| description |
A novel octanuclear manganese metalladiazamacrocycle (1) was synthesized employing a new pentadentate ligand N-methacryl-5-methylsalicylhydrazide (H3mamshz) by supramolecular self assembly. The backbone of this metal-organic assembly is a repeating unit of Mn–N–N–Mn linkage that extends to complete a 24-membered cyclic structure involving 8 manganese(III) centers. Successive manganese centers are in an octanuclear cyclic structure. The temperature-dependent magnetic properties show a typical weakly coupled antiferromagnetic behaviour. DOI: http://dx.doi.org/10.4314/bcse.v28i3.9 |
| topic |
Manganese Octanuclear Metalladiazamacrocycle Pentadentate ligand Antiferromagnetic behavior |
| url |
http://www.ajol.info/index.php/bcse/article/view/108084 |
| work_keys_str_mv |
AT fdang novel24memberedoctanuclearmanganeseiiimetallacrown AT dzhao novel24memberedoctanuclearmanganeseiiimetallacrown AT hguo novel24memberedoctanuclearmanganeseiiimetallacrown AT kwlei novel24memberedoctanuclearmanganeseiiimetallacrown |
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1725580875365613568 |