(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide
There are two independent molecules (A and B) in the asymmetric unit of the title compound, C11H19N3S. In molecule B, two C atoms and the associated H atoms of the cyclohexene ring are disordered over two sets of sites with a site occupancy ratio of 0.649 (7):0.351 (7). The N—N—C—N fragments of the...
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International Union of Crystallography
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doaj-633fb8972cbe4173b0755cc6ddf2fd652020-11-24T23:17:08ZengInternational Union of CrystallographyIUCrData2414-31462017-04-0124x17051310.1107/S2414314617005132sj4102(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamideMourad Fawzi0Aziz Auhmani1Moulay Youssef Ait Itto2Abdelkhalek Riahi3Sylviane Chevreux4El Mostafa Ketatni5Laboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, MoroccoLaboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, MoroccoLaboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, MoroccoInstitute of Molecular Chemistry of Reims, CNRS UMR 7312 Bat. Europol'Agro, Moulin of the Housse UFR Sciences, BP 1039-51687 Reims Cedex 2, FranceInstitute of Molecular Chemistry of Reims, CNRS UMR 7312 Bat. Europol'Agro, Moulin of the Housse UFR Sciences, BP 1039-51687 Reims Cedex 2, FranceLaboratory of Applied Spectro-Chemistry and Environment, University Sultan Moulay Slimane, Faculty of Science and Technology, PO Box 523, Beni-Mellal, MoroccoThere are two independent molecules (A and B) in the asymmetric unit of the title compound, C11H19N3S. In molecule B, two C atoms and the associated H atoms of the cyclohexene ring are disordered over two sets of sites with a site occupancy ratio of 0.649 (7):0.351 (7). The N—N—C—N fragments of the hydrazinecarbothioamide segments of both molecules are not planar, with a torsion angle of −5.8 (3)° for A and 11.6 (3)° for B. The stability of the conformations of both molecules is aided by the formation of intramolecular N—H...N hydrogen bonds. In the crystal, N—H...S hydrogen bonds link like molecules into R22(8) A + B dimers. These dimers are interconnected by additional N—H...S contacts, forming chains along the c-axis direction. The structure was refined as a two-component inversion twin.http://scripts.iucr.org/cgi-bin/paper?S2414314617005132crystal structurehydrazinecarbothiamidenatural producthydrogen bond |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mourad Fawzi Aziz Auhmani Moulay Youssef Ait Itto Abdelkhalek Riahi Sylviane Chevreux El Mostafa Ketatni |
spellingShingle |
Mourad Fawzi Aziz Auhmani Moulay Youssef Ait Itto Abdelkhalek Riahi Sylviane Chevreux El Mostafa Ketatni (2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide IUCrData crystal structure hydrazinecarbothiamide natural product hydrogen bond |
author_facet |
Mourad Fawzi Aziz Auhmani Moulay Youssef Ait Itto Abdelkhalek Riahi Sylviane Chevreux El Mostafa Ketatni |
author_sort |
Mourad Fawzi |
title |
(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
title_short |
(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
title_full |
(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
title_fullStr |
(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
title_full_unstemmed |
(2E)-N-Methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
title_sort |
(2e)-n-methyl-2-[1-(4-methylcyclohex-3-en-1-yl)ethylidene]hydrazinecarbothioamide |
publisher |
International Union of Crystallography |
series |
IUCrData |
issn |
2414-3146 |
publishDate |
2017-04-01 |
description |
There are two independent molecules (A and B) in the asymmetric unit of the title compound, C11H19N3S. In molecule B, two C atoms and the associated H atoms of the cyclohexene ring are disordered over two sets of sites with a site occupancy ratio of 0.649 (7):0.351 (7). The N—N—C—N fragments of the hydrazinecarbothioamide segments of both molecules are not planar, with a torsion angle of −5.8 (3)° for A and 11.6 (3)° for B. The stability of the conformations of both molecules is aided by the formation of intramolecular N—H...N hydrogen bonds. In the crystal, N—H...S hydrogen bonds link like molecules into R22(8) A + B dimers. These dimers are interconnected by additional N—H...S contacts, forming chains along the c-axis direction. The structure was refined as a two-component inversion twin. |
topic |
crystal structure hydrazinecarbothiamide natural product hydrogen bond |
url |
http://scripts.iucr.org/cgi-bin/paper?S2414314617005132 |
work_keys_str_mv |
AT mouradfawzi 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide AT azizauhmani 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide AT moulayyoussefaititto 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide AT abdelkhalekriahi 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide AT sylvianechevreux 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide AT elmostafaketatni 2enmethyl214methylcyclohex3en1ylethylidenehydrazinecarbothioamide |
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