(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide
In the title compound, C18H21N3O, the dihedral angle between the pyridine and benzene rings is 30.53 (7)° and the C—C=N—C torsion angle is −170.6 (2)°. An intramolecular N—H...N hydrogen bond generates an S(6) ring. In the crystal, very weak C—H...O hydrogen bonds link the molecules into C(8) [101]...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017-11-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617017023 |
| id |
doaj-63aa2ad0ba93472a99ae2e522ee5b746 |
|---|---|
| record_format |
Article |
| spelling |
doaj-63aa2ad0ba93472a99ae2e522ee5b7462020-11-24T22:45:47ZengInternational Union of CrystallographyIUCrData2414-31462017-11-01211x17170210.1107/S2414314617017023hb4184(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamideŞehriman Atalay0Semra Gerçeker1Seher Meral2Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, Kurupelit, 55139 Samsun, TurkeyDepartment of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, Kurupelit, 55139 Samsun, TurkeyDepartment of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayıs University, Kurupelit, 55139 Samsun, TurkeyIn the title compound, C18H21N3O, the dihedral angle between the pyridine and benzene rings is 30.53 (7)° and the C—C=N—C torsion angle is −170.6 (2)°. An intramolecular N—H...N hydrogen bond generates an S(6) ring. In the crystal, very weak C—H...O hydrogen bonds link the molecules into C(8) [101] chains. The tert-butyl methyl groups are disordered over two sets of sites in a 0.783 (4):0.217 (4) ratio.http://scripts.iucr.org/cgi-bin/paper?S2414314617017023crystal structureSchiff basehydrogen bonding |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Şehriman Atalay Semra Gerçeker Seher Meral |
| spellingShingle |
Şehriman Atalay Semra Gerçeker Seher Meral (E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide IUCrData crystal structure Schiff base hydrogen bonding |
| author_facet |
Şehriman Atalay Semra Gerçeker Seher Meral |
| author_sort |
Şehriman Atalay |
| title |
(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide |
| title_short |
(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide |
| title_full |
(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide |
| title_fullStr |
(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide |
| title_full_unstemmed |
(E)-N-{3-[(m-Tolylimino)methyl]pyridin-2-yl}pivalamide |
| title_sort |
(e)-n-{3-[(m-tolylimino)methyl]pyridin-2-yl}pivalamide |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2017-11-01 |
| description |
In the title compound, C18H21N3O, the dihedral angle between the pyridine and benzene rings is 30.53 (7)° and the C—C=N—C torsion angle is −170.6 (2)°. An intramolecular N—H...N hydrogen bond generates an S(6) ring. In the crystal, very weak C—H...O hydrogen bonds link the molecules into C(8) [101] chains. The tert-butyl methyl groups are disordered over two sets of sites in a 0.783 (4):0.217 (4) ratio. |
| topic |
crystal structure Schiff base hydrogen bonding |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2414314617017023 |
| work_keys_str_mv |
AT sehrimanatalay en3mtolyliminomethylpyridin2ylpivalamide AT semragerceker en3mtolyliminomethylpyridin2ylpivalamide AT sehermeral en3mtolyliminomethylpyridin2ylpivalamide |
| _version_ |
1725687495800127488 |