Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte
The rapidly growing Li-ion battery market has generated considerable demand for Li-ion batteries with improved performance and stability. All-solid-state Li-ion batteries offer promising safety and manufacturing enhancements. Herein, we examine the effect of substitutional doping at three cation sit...
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doaj-643ca7625b5d43d4bc93568c9c3fc00e2021-01-28T00:01:52ZengMDPI AGMicromachines2072-666X2021-01-011213413410.3390/mi12020134Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State ElectrolyteMinji Kim0Gwanhyeon Kim1Heechul Lee2Department of Advanced Materials Engineering, Korea Polytechnic University, Gyeonggi 15073, KoreaDepartment of Advanced Materials Engineering, Korea Polytechnic University, Gyeonggi 15073, KoreaDepartment of Advanced Materials Engineering, Korea Polytechnic University, Gyeonggi 15073, KoreaThe rapidly growing Li-ion battery market has generated considerable demand for Li-ion batteries with improved performance and stability. All-solid-state Li-ion batteries offer promising safety and manufacturing enhancements. Herein, we examine the effect of substitutional doping at three cation sites in garnet-type Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> (LLZO) oxide ceramics produced by a sol–gel synthesis technique with the aim of enhancing the properties of solid-state electrolytes for use in all-solid-state Li-ion batteries. Building on the results of mono-doping experiments with different doping elements and sites—Al, Ga, and Ge at the Li<sup>+</sup> site; Rb at the La<sup>3+</sup> site; and Ta and Nb at the Zr<sup>4+</sup> site—we designed co-doped (Ga, Al, or Rb with Nb) and tri-doped (Ga or Al with Rb and Nb) samples by compositional optimization, and achieved a LLZO ceramic with a pure cubic phase, almost no secondary phase, uniform grain structure, and excellent Li-ion conductivity. The findings extend the current literature on the doping of LLZO ceramics and highlight the potential of the sol–gel method for the production of solid-state electrolytes.https://www.mdpi.com/2072-666X/12/2/134solid state electrolyteall-solid-state batterylithium-ion batterygarnet oxidedopingco-doping |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Minji Kim Gwanhyeon Kim Heechul Lee |
spellingShingle |
Minji Kim Gwanhyeon Kim Heechul Lee Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte Micromachines solid state electrolyte all-solid-state battery lithium-ion battery garnet oxide doping co-doping |
author_facet |
Minji Kim Gwanhyeon Kim Heechul Lee |
author_sort |
Minji Kim |
title |
Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte |
title_short |
Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte |
title_full |
Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte |
title_fullStr |
Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte |
title_full_unstemmed |
Tri-Doping of Sol–Gel Synthesized Garnet-Type Oxide Solid-State Electrolyte |
title_sort |
tri-doping of sol–gel synthesized garnet-type oxide solid-state electrolyte |
publisher |
MDPI AG |
series |
Micromachines |
issn |
2072-666X |
publishDate |
2021-01-01 |
description |
The rapidly growing Li-ion battery market has generated considerable demand for Li-ion batteries with improved performance and stability. All-solid-state Li-ion batteries offer promising safety and manufacturing enhancements. Herein, we examine the effect of substitutional doping at three cation sites in garnet-type Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> (LLZO) oxide ceramics produced by a sol–gel synthesis technique with the aim of enhancing the properties of solid-state electrolytes for use in all-solid-state Li-ion batteries. Building on the results of mono-doping experiments with different doping elements and sites—Al, Ga, and Ge at the Li<sup>+</sup> site; Rb at the La<sup>3+</sup> site; and Ta and Nb at the Zr<sup>4+</sup> site—we designed co-doped (Ga, Al, or Rb with Nb) and tri-doped (Ga or Al with Rb and Nb) samples by compositional optimization, and achieved a LLZO ceramic with a pure cubic phase, almost no secondary phase, uniform grain structure, and excellent Li-ion conductivity. The findings extend the current literature on the doping of LLZO ceramics and highlight the potential of the sol–gel method for the production of solid-state electrolytes. |
topic |
solid state electrolyte all-solid-state battery lithium-ion battery garnet oxide doping co-doping |
url |
https://www.mdpi.com/2072-666X/12/2/134 |
work_keys_str_mv |
AT minjikim tridopingofsolgelsynthesizedgarnettypeoxidesolidstateelectrolyte AT gwanhyeonkim tridopingofsolgelsynthesizedgarnettypeoxidesolidstateelectrolyte AT heechullee tridopingofsolgelsynthesizedgarnettypeoxidesolidstateelectrolyte |
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