Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III)
Fe-Ionic Imprinted Polymer (IIP) from polyeugenol as base polymer and polyethylene glycol diglycidyl ether (PEGDE) as cross-linking agent had been synthesized to adsorb Fe(III) from aqueous media. The non-imprinting material (NIP) and polyeugenol were used in the adsorption study as control. Synthes...
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doaj-64f3c06dc255483c8e681989b939fa6d2020-11-24T22:05:12ZengUniversitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782015-11-0115330531410.22146/ijc.2120014298Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III)Muhammad Cholid Djunaidi0Jumina Jumina1Dwi Siswanta2Mathias Ulbricht3Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang, Semarang 50275Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281Lehrstuhl für Technische Chemie II, Fakultätfür Chemie, Universität Duisburg-Essen, 45117 EssenFe-Ionic Imprinted Polymer (IIP) from polyeugenol as base polymer and polyethylene glycol diglycidyl ether (PEGDE) as cross-linking agent had been synthesized to adsorb Fe(III) from aqueous media. The non-imprinting material (NIP) and polyeugenol were used in the adsorption study as control. Synthesis work included polymerization, template uploading, crosslinking and template removal, optimized for different template ion upload pH and concentrations. The polymers were characterized by FTIR spectroscopy, XRD and SEM-EDX, followed by adsorption test to study the adsorption kinetics and isotherms for all adsorbents. Selective adsorption study of IIP was carried out using binary mixtures of Fe(III) and Cr(III), Pb(II), Cd(II). Experimental results showed that the optimum conditions for the synthesis was template upload pH of 3, Fe/polyeugenol ratio of 1 mg/g, while the optimum adsorption pH was 3. The adsorption mechanism of Fe(III) on all adsorbents was dominated by hydrogen bond formation. The adsorption kinetics followed the pseudo-second-order model while the equilibrium data was best explained by the Langmuir isotherm model. The adsorption capacity of Fe(III) on the IIP was 12.73 mg/g, higher than that of the other adsorbents. Results also show that IIP-Fe was more selective toward Fe than NIP by 2.69 (Cd), 1.66 (Cr) and 1.6 (Pb) fold, respectively.https://jurnal.ugm.ac.id/ijc/article/view/21200polyeugenolionic imprinted Fe adsorbentselective adsorptionPEGDE |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Muhammad Cholid Djunaidi Jumina Jumina Dwi Siswanta Mathias Ulbricht |
spellingShingle |
Muhammad Cholid Djunaidi Jumina Jumina Dwi Siswanta Mathias Ulbricht Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) Indonesian Journal of Chemistry polyeugenol ionic imprinted Fe adsorbent selective adsorption PEGDE |
author_facet |
Muhammad Cholid Djunaidi Jumina Jumina Dwi Siswanta Mathias Ulbricht |
author_sort |
Muhammad Cholid Djunaidi |
title |
Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) |
title_short |
Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) |
title_full |
Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) |
title_fullStr |
Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) |
title_full_unstemmed |
Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III) |
title_sort |
synthesis of fe ionic-imprinted polyeugenol using polyethylene glycol diglycidilether as cross-linking agent for sorption of fe(iii) |
publisher |
Universitas Gadjah Mada |
series |
Indonesian Journal of Chemistry |
issn |
1411-9420 2460-1578 |
publishDate |
2015-11-01 |
description |
Fe-Ionic Imprinted Polymer (IIP) from polyeugenol as base polymer and polyethylene glycol diglycidyl ether (PEGDE) as cross-linking agent had been synthesized to adsorb Fe(III) from aqueous media. The non-imprinting material (NIP) and polyeugenol were used in the adsorption study as control. Synthesis work included polymerization, template uploading, crosslinking and template removal, optimized for different template ion upload pH and concentrations. The polymers were characterized by FTIR spectroscopy, XRD and SEM-EDX, followed by adsorption test to study the adsorption kinetics and isotherms for all adsorbents. Selective adsorption study of IIP was carried out using binary mixtures of Fe(III) and Cr(III), Pb(II), Cd(II). Experimental results showed that the optimum conditions for the synthesis was template upload pH of 3, Fe/polyeugenol ratio of 1 mg/g, while the optimum adsorption pH was 3. The adsorption mechanism of Fe(III) on all adsorbents was dominated by hydrogen bond formation. The adsorption kinetics followed the pseudo-second-order model while the equilibrium data was best explained by the Langmuir isotherm model. The adsorption capacity of Fe(III) on the IIP was 12.73 mg/g, higher than that of the other adsorbents. Results also show that IIP-Fe was more selective toward Fe than NIP by 2.69 (Cd), 1.66 (Cr) and 1.6 (Pb) fold, respectively. |
topic |
polyeugenol ionic imprinted Fe adsorbent selective adsorption PEGDE |
url |
https://jurnal.ugm.ac.id/ijc/article/view/21200 |
work_keys_str_mv |
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1716599969515831296 |