Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc
The tetranuclear title complex, [Zn4(C19H20N2O4)2(CH3COO)4], is formed from two dinuclear motifs related by an inversion centre. The two crystallographically independent ZnII ions in the asymmetric unit are in different coordination environments. One is square-based pyramidal with one O atom of an a...
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doaj-652ead9da60e4cf6b5edc0fab0c6ad8e2020-11-24T23:31:38ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112m217m21810.1107/S2056989015020551pj2024Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazincXue Cai0Hui Ning1Department of Chemistry, Mudanjiang Normal University, Mudanjiang 157011, People's Republic of ChinaDepartment of Chemistry, Mudanjiang Normal University, Mudanjiang 157011, People's Republic of ChinaThe tetranuclear title complex, [Zn4(C19H20N2O4)2(CH3COO)4], is formed from two dinuclear motifs related by an inversion centre. The two crystallographically independent ZnII ions in the asymmetric unit are in different coordination environments. One is square-based pyramidal with one O atom of an acetate group occupying the axial position and two N and O atoms of one bmspd [H2bmspd = N,N′-bis(3-methoxysalicylidene)propylene-1,3-diamine] Schiff base ligand forming the basal plane. The other ZnII atom is six-coordinated by four O atoms of the bmspd ligand forming the equatoral plane and two O atoms of different acetate groups located in the axial positions. As a result, the two phenolic planes of the bicompartmental Schiff base ligand are distorted slightly. However, the planes of the two Schiff base ligands are parallel. In addition, the Zn—N and Zn—O bond lengths span the reasonable ranges 2.062 (2)–2.073 (2) and 1.9261 (15)–2.4356 (16) Å, respectively. The Zn...Zn distances separated by phenolic O atoms are 3.2466 (4) Å while the Zn...Zn distances bridged by acetate groups are 5.9835 (6) Å. The tetranuclear moieties are connected by van der Waals interactions, and form a chain along c axis.http://scripts.iucr.org/cgi-bin/paper?S2056989015020551crystal structurezincSchiff baseacetate |
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DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xue Cai Hui Ning |
spellingShingle |
Xue Cai Hui Ning Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc Acta Crystallographica Section E: Crystallographic Communications crystal structure zinc Schiff base acetate |
author_facet |
Xue Cai Hui Ning |
author_sort |
Xue Cai |
title |
Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
title_short |
Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
title_full |
Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
title_fullStr |
Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
title_full_unstemmed |
Crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
title_sort |
crystal structure of di-μ-acetato-diacetatobis(μ-6,6′-dimethoxy-2,2′-{[(propane-1,3-diylbis(azanylylidene)]bis(methanylylidene)}diphenolato)tetrazinc |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2015-12-01 |
description |
The tetranuclear title complex, [Zn4(C19H20N2O4)2(CH3COO)4], is formed from two dinuclear motifs related by an inversion centre. The two crystallographically independent ZnII ions in the asymmetric unit are in different coordination environments. One is square-based pyramidal with one O atom of an acetate group occupying the axial position and two N and O atoms of one bmspd [H2bmspd = N,N′-bis(3-methoxysalicylidene)propylene-1,3-diamine] Schiff base ligand forming the basal plane. The other ZnII atom is six-coordinated by four O atoms of the bmspd ligand forming the equatoral plane and two O atoms of different acetate groups located in the axial positions. As a result, the two phenolic planes of the bicompartmental Schiff base ligand are distorted slightly. However, the planes of the two Schiff base ligands are parallel. In addition, the Zn—N and Zn—O bond lengths span the reasonable ranges 2.062 (2)–2.073 (2) and 1.9261 (15)–2.4356 (16) Å, respectively. The Zn...Zn distances separated by phenolic O atoms are 3.2466 (4) Å while the Zn...Zn distances bridged by acetate groups are 5.9835 (6) Å. The tetranuclear moieties are connected by van der Waals interactions, and form a chain along c axis. |
topic |
crystal structure zinc Schiff base acetate |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015020551 |
work_keys_str_mv |
AT xuecai crystalstructureofdimacetatodiacetatobism66dimethoxy22propane13diylbisazanylylidenebismethanylylidenediphenolatotetrazinc AT huining crystalstructureofdimacetatodiacetatobism66dimethoxy22propane13diylbisazanylylidenebismethanylylidenediphenolatotetrazinc |
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1725536887390601216 |