Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate)
Composites based on unsaturated polyester (UPe) resins and fumed silica AEROSIL® RY 50, NY 50, RX 50 and NAX 50, as well as graphite, TiO2 or organically modified clay CLOISITE 30B were prepared in order to investigate the influence of reinforcing agents on the mechanical properties of c...
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doaj-6671af42dcd94b0b9d26d06f0a1890fa2020-11-24T23:10:19ZengAssociation of Chemical Engineers of SerbiaHemijska Industrija 0367-598X2217-74262013-01-0167691392210.2298/HEMIND130930077M0367-598X1300077MMechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate)Marinković Aleksandar D.0Radoman Tijana1Džunuzović Enis S.2Džunuzović Jasna V.3Spasojević Pavle4Isailović Bojana5Bugarski Branko6Faculty of Technology and Metallurgy, BelgradeFaculty of Technology and Metallurgy, Innovation center, BelgradeFaculty of Technology and Metallurgy, BelgradeInstitute of Chemistry, Technology and Metallurgy (ICTM)-Center of Chemistry, BelgradeFaculty of Technology and Metallurgy, BelgradeFaculty of Technology and Metallurgy, BelgradeFaculty of Technology and Metallurgy, BelgradeComposites based on unsaturated polyester (UPe) resins and fumed silica AEROSIL® RY 50, NY 50, RX 50 and NAX 50, as well as graphite, TiO2 or organically modified clay CLOISITE 30B were prepared in order to investigate the influence of reinforcing agents on the mechanical properties of composites. Unsaturated polyester resins were synthesized from maleic anhydride and products of glycolysis, obtained by depolymerization of poly(ethylene terephthalate) with dipropylene glycol (UPe1 resin) and triethylene glycol (UPe2 resin) in the presence of tetrabutyl titanate catalyst. The obtained unsaturated polyesters were characterized by FTIR spectroscopy, acid and hydroxyl values, and their mechanical properties were also examined. Significant increase of the tensile modulus, tensile strength and decrease of the elongation at break was observed for composites prepared after addition of 10 wt.% of graphite or 10 wt.% of TiO2 to the UPe resins, indicating strong interaction between matrix and filler particles. On the other hand, nanocomposites prepared using UPe2 and hydrophobically modified silica nanoparticles showed lower tensile strength and tensile modulus than polymer matrix. The presence of CLOISITE 30B had no significant influence on the mechanical properties of UPe1, while tensile strength and tensile modulus of UPe2 increased after adding 10 wt.% of clay. [Projekat Ministarstva nauke Republike Srbije, br. 172013]http://www.doiserbia.nb.rs/img/doi/0367-598X/2013/0367-598X1300077M.pdfpoly(ethylene terephthalate)chemical recyclingcompositesmechanical properties |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Marinković Aleksandar D. Radoman Tijana Džunuzović Enis S. Džunuzović Jasna V. Spasojević Pavle Isailović Bojana Bugarski Branko |
spellingShingle |
Marinković Aleksandar D. Radoman Tijana Džunuzović Enis S. Džunuzović Jasna V. Spasojević Pavle Isailović Bojana Bugarski Branko Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) Hemijska Industrija poly(ethylene terephthalate) chemical recycling composites mechanical properties |
author_facet |
Marinković Aleksandar D. Radoman Tijana Džunuzović Enis S. Džunuzović Jasna V. Spasojević Pavle Isailović Bojana Bugarski Branko |
author_sort |
Marinković Aleksandar D. |
title |
Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
title_short |
Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
title_full |
Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
title_fullStr |
Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
title_full_unstemmed |
Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
title_sort |
mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate) |
publisher |
Association of Chemical Engineers of Serbia |
series |
Hemijska Industrija |
issn |
0367-598X 2217-7426 |
publishDate |
2013-01-01 |
description |
Composites based on unsaturated polyester (UPe) resins and fumed silica
AEROSIL® RY 50, NY 50, RX 50 and NAX 50, as well as graphite, TiO2 or
organically modified clay CLOISITE 30B were prepared in order to investigate
the influence of reinforcing agents on the mechanical properties of
composites. Unsaturated polyester resins were synthesized from maleic
anhydride and products of glycolysis, obtained by depolymerization of
poly(ethylene terephthalate) with dipropylene glycol (UPe1 resin) and
triethylene glycol (UPe2 resin) in the presence of tetrabutyl titanate
catalyst. The obtained unsaturated polyesters were characterized by FTIR
spectroscopy, acid and hydroxyl values, and their mechanical properties were
also examined. Significant increase of the tensile modulus, tensile strength
and decrease of the elongation at break was observed for composites prepared
after addition of 10 wt.% of graphite or 10 wt.% of TiO2 to the UPe resins,
indicating strong interaction between matrix and filler particles. On the
other hand, nanocomposites prepared using UPe2 and hydrophobically modified
silica nanoparticles showed lower tensile strength and tensile modulus than
polymer matrix. The presence of CLOISITE 30B had no significant influence on
the mechanical properties of UPe1, while tensile strength and tensile modulus
of UPe2 increased after adding 10 wt.% of clay. [Projekat Ministarstva nauke
Republike Srbije, br. 172013] |
topic |
poly(ethylene terephthalate) chemical recycling composites mechanical properties |
url |
http://www.doiserbia.nb.rs/img/doi/0367-598X/2013/0367-598X1300077M.pdf |
work_keys_str_mv |
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