Crystal structure of bis(isonicotinamide-κN1)bis(thiocyanato-κN)zinc
The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thiocyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetrahedrally coordinated into a discrete c...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2016-07-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016008963 |
Summary: | The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thiocyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetrahedrally coordinated into a discrete complex by the N atoms of two symmetry-related thiocyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by intermolecular C—H...O and N—H...O, and weak intermolecular N—H...S hydrogen-bonding interactions into a three-dimensional network. |
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ISSN: | 2056-9890 |