E-Beam Effects on Poly(Xylitol Dicarboxylate-co-diol Dicarboxylate) Elastomers Tailored by Adjusting Monomer Chain Length

• Main Authors: Marta Piątek-Hnat, Kuba Bomba, Janusz P. Kowalski-Stankiewicz, Jakub Pęksiński, Agnieszka Kozłowska, Jacek G. Sośnicki, Tomasz J. Idzik, Beata Schmidt, Krzysztof Kowalczyk, Marta Walo, Grzegorz Mikołajczak, Agnieszka Kochmańska
• Format: Article
• Language: English
• Published: MDPI AG 2021-04-01
• Series: Materials
• Subjects: xylitol; biodegradable elastomers; radiation modification; e-beam; mechanical and thermal properties
• Online Access: https://www.mdpi.com/1996-1944/14/7/1765

Poly(xylitol dicarboxylate-co-diol dicarboxylate) elastomers can by synthesized using wide variety of monomers with different chain lengths. Obtained materials are all biodegradable, thermally stable elastomers, but their specific properties like glass transition temperature, degradation susceptibility, and mechanical moduli can be tailored for a specific application. Therefore, we synthesized eight elastomers using a combination of two dicarboxylic acids, namely suberic and sebacic acid, and four different diols, namely ethanediol, 1,3-propanediol, 1,4-buanediol, and 1,5-pentanediol. Materials were further modified by e-beam treatment with a dose of 100 kGy. Materials both before and after radiation modification were tested using tensile tests, gel fraction determination, ¹H NMR, and ¹³C NMR. Thermal properties were tested by Differential Scanning Calorimetry (DSC), Dynamic Thermomechanical Analysis (DMTA) and Thermogravimetric Analysis (TGA). Degradation susceptibility to both enzymatic and hydrolytic degradation was also determined.