Effects of marine fuel sulfur restrictions on particle number concentrations and size distributions in ship plumes in the Baltic Sea

• Main Authors: S. D. Seppälä, J. Kuula, A.-P. Hyvärinen, S. Saarikoski, T. Rönkkö, J. Keskinen, J.-P. Jalkanen, H. Timonen
• Format: Article
• Language: English
• Published: Copernicus Publications 2021-03-01
• Series: Atmospheric Chemistry and Physics
• Online Access: https://acp.copernicus.org/articles/21/3215/2021/acp-21-3215-2021.pdf
• ISSN: 1680-7316; 1680-7324

<p>Exhaust emissions from shipping are a major contributor to particle concentrations in coastal and marine areas. Previously, the marine fuel sulfur content (FSC) was restricted globally to 4.5 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M1" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="de291dba9c17654b59b65ed50c878159"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00001.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00001.png"/></svg:svg></span></span>, but the limit was changed to 3.5 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M2" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="3969ef12f91258f7b3a89480b37dd106"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00002.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00002.png"/></svg:svg></span></span> at the beginning of 2012 and further down to 0.5 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M3" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="3ef0ae0c4ff2b2268085dfc8ea7064e1"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00003.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00003.png"/></svg:svg></span></span> in January 2020. In sulfur emission control areas (SECA), the limits are stricter: the FSC restriction was originally 1.50 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M4" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="1e3cecade7b558bb88aa08ff21caa790"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00004.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00004.png"/></svg:svg></span></span>, but it decreased to 1.00 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M5" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="d7b8eb3155f9c17193c411ba23bf57e9"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00005.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00005.png"/></svg:svg></span></span> in July 2010 and again to 0.10 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M6" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="b5e8b92fa7366cf1682ebb26e3889cf9"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00006.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00006.png"/></svg:svg></span></span> in January 2015. In this work, the effects of the FSC restrictions on particle number concentrations (PNCs) and particle number size distributions (NSDs) are studied in the Baltic Sea SECA. Measurements were made on a small island (Utö, Finland; <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M7" display="inline" overflow="scroll" dspmath="mathml"><mrow><mn mathvariant="normal">59</mn><msup><mi/><mo>∘</mo></msup><msup><mn mathvariant="normal">46</mn><mo>′</mo></msup><mn mathvariant="normal">50</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="45pt" height="11pt" class="svg-formula" dspmath="mathimg" md5hash="361f20c8fea6feb4cadec56e32b32c7e"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00007.svg" width="45pt" height="11pt" src="acp-21-3215-2021-ie00007.png"/></svg:svg></span></span> N, <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M8" display="inline" overflow="scroll" dspmath="mathml"><mrow><mn mathvariant="normal">21</mn><msup><mi/><mo>∘</mo></msup><msup><mn mathvariant="normal">22</mn><mo>′</mo></msup><mn mathvariant="normal">23</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="45pt" height="11pt" class="svg-formula" dspmath="mathimg" md5hash="909ba35c84c6ed1dfcd1cdccba6baf67"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00008.svg" width="45pt" height="11pt" src="acp-21-3215-2021-ie00008.png"/></svg:svg></span></span> E) between 2007 and 2016. Ship plumes were extracted from the particle number size distribution data, and the effects of the FSC restrictions on the observed plumes as well as on the ambient concentrations were investigated.</p> <p>Altogether, 42 322 analyzable plumes were identified during the 10-year measurement period. The results showed that both changes in the FSC restrictions reduced the PNCs of the plumes. The latter restriction (to 0.10 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M9" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="eba4411a719b777ebc14eb6e64579718"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00009.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00009.png"/></svg:svg></span></span> in January 2015) also decreased the ambient particle number concentrations, as a significant portion of particles in the area originated from ship plumes that were diluted beyond the plume detection limits. The overall change in the PNCs of the plumes and ambient air was 27 and 32 %, respectively, for the total FSC change from 1.50 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M10" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="cb5d3f272146d5ca83511492f9c758c3"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00010.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00010.png"/></svg:svg></span></span> to 0.10 <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M11" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>m</mi><mo>/</mo><mi>m</mi><mi mathvariant="italic">%</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="37pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="7d0b91af68789ab5e41ac295c43f1b5d"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-21-3215-2021-ie00011.svg" width="37pt" height="14pt" src="acp-21-3215-2021-ie00011.png"/></svg:svg></span></span>. The decrease in the plume particle number concentration was caused mostly by a decrease in the concentration of particle sizes of between approximately 33 and 144 nm. The latter restriction also reduced the geometric mean diameter of the particles, which was probably caused by the fuel type change from residual oil to distillates during the latter restriction. The PNC was larger for the plumes measured at daytime than for those measured at nighttime, likely because of the photochemical aging of particles due to UV light. The difference decreased with decreasing FSC, indicating that a lower FSC also has an impact on the atmospheric processing of ship plumes.</p>