Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes
A new trifluoromethylsulfonate salt of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol, (HL)CF3SO3, and its copper(II) and cobalt(III) complexes, [CuL(OH2)]CF3SO3·0.5H2O (1) and [CoL2]CF3SO3·CH3OH (2), were prepared and characterized by physico-chemical methods and single crystal X-ray...
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Slovenian Chemical Society
2016-10-01
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doaj-67e6eecf09704009a4a7d10786fb8fbb2020-11-24T23:48:48ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552016-10-0163485686310.17344/acsi.2016.2795401Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexesYa-Li Sang0Xue-Song LinWei-Dong SunChifeng UniversityA new trifluoromethylsulfonate salt of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol, (HL)CF3SO3, and its copper(II) and cobalt(III) complexes, [CuL(OH2)]CF3SO3·0.5H2O (1) and [CoL2]CF3SO3·CH3OH (2), were prepared and characterized by physico-chemical methods and single crystal X-ray analysis. A trifluoromethylsulfonate anion is present in each of the compounds. The Cu atom in complex 1 is coordinated by the phenolate O, imino N and pyridine N atoms of L ligand, giving square planar geometry. The Co atom in complex 2 is coordinated by two phenolate O, two imino N and two pyridine N atoms from two L ligands, giving octahedral geometry. The three compounds were tested in vitro for their antibacterial activities.https://journals.matheo.si/index.php/ACSi/article/view/2795Schiff baseCopperCobaltSynthesisCrystal structureAntibacterial activity |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ya-Li Sang Xue-Song Lin Wei-Dong Sun |
spellingShingle |
Ya-Li Sang Xue-Song Lin Wei-Dong Sun Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes Acta Chimica Slovenica Schiff base Copper Cobalt Synthesis Crystal structure Antibacterial activity |
author_facet |
Ya-Li Sang Xue-Song Lin Wei-Dong Sun |
author_sort |
Ya-Li Sang |
title |
Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes |
title_short |
Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes |
title_full |
Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes |
title_fullStr |
Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes |
title_full_unstemmed |
Synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(II) and cobalt(III) complexes |
title_sort |
synthesis, crystal structures and antibacterial activities of trifluoromethylsulfonate salts of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol and its copper(ii) and cobalt(iii) complexes |
publisher |
Slovenian Chemical Society |
series |
Acta Chimica Slovenica |
issn |
1318-0207 1580-3155 |
publishDate |
2016-10-01 |
description |
A new trifluoromethylsulfonate salt of 2-[(3-chloropyridinium-2-yl)hydrazonomethyl]-6-methoxyphenol, (HL)CF3SO3, and its copper(II) and cobalt(III) complexes, [CuL(OH2)]CF3SO3·0.5H2O (1) and [CoL2]CF3SO3·CH3OH (2), were prepared and characterized by physico-chemical methods and single crystal X-ray analysis. A trifluoromethylsulfonate anion is present in each of the compounds. The Cu atom in complex 1 is coordinated by the phenolate O, imino N and pyridine N atoms of L ligand, giving square planar geometry. The Co atom in complex 2 is coordinated by two phenolate O, two imino N and two pyridine N atoms from two L ligands, giving octahedral geometry. The three compounds were tested in vitro for their antibacterial activities. |
topic |
Schiff base Copper Cobalt Synthesis Crystal structure Antibacterial activity |
url |
https://journals.matheo.si/index.php/ACSi/article/view/2795 |
work_keys_str_mv |
AT yalisang synthesiscrystalstructuresandantibacterialactivitiesoftrifluoromethylsulfonatesaltsof23chloropyridinium2ylhydrazonomethyl6methoxyphenolanditscopperiiandcobaltiiicomplexes AT xuesonglin synthesiscrystalstructuresandantibacterialactivitiesoftrifluoromethylsulfonatesaltsof23chloropyridinium2ylhydrazonomethyl6methoxyphenolanditscopperiiandcobaltiiicomplexes AT weidongsun synthesiscrystalstructuresandantibacterialactivitiesoftrifluoromethylsulfonatesaltsof23chloropyridinium2ylhydrazonomethyl6methoxyphenolanditscopperiiandcobaltiiicomplexes |
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1725484425359130624 |