Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance
Metal oxides have been attractive as high-capacity anode materials for lithium-ion batteries. However, oxide anodes encounter drastic volumetric changes during lithium ion storage through the conversion reaction and alloying/dealloying processes, leading to rapid capacity decay and poor cycling stab...
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doaj-68b4d08675d14a1d828376d4f3b485922020-11-25T02:21:22ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-12-01710.3389/fchem.2019.00878496416Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage PerformanceShuli Jiang0Shuli Jiang1Ruiming Huang2Wenchang Zhu3Wenchang Zhu4Xiangyi Li5Xiangyi Li6Yue Zhao7Yue Zhao8Zhixiang Gao9Zhixiang Gao10Lijun Gao11Lijun Gao12Jianqing Zhao13Jianqing Zhao14College of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaDepartment of Chemistry, Rutgers-Newark, The State University of New Jersey, Newark, NJ, United StatesCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaCollege of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou, ChinaKey Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, ChinaMetal oxides have been attractive as high-capacity anode materials for lithium-ion batteries. However, oxide anodes encounter drastic volumetric changes during lithium ion storage through the conversion reaction and alloying/dealloying processes, leading to rapid capacity decay and poor cycling stability. Here, we report a free-standing SnO2@reduced graphene oxide (SnO2@rGO) composite anode, in which SnO2 nanoparticles are tightly wrapped within wrinkled rGO sheets. The SnO2@rGO sheet is assembled in high porosity via an anti-solvent-assisted precipitation of dispersed SnO2 nanoparticles and graphene oxide sheets in the distilled water, followed by the filtration and post-annealing processes. Significantly enhanced lithium storage performance has been obtained of the SnO2@rGO anode compared with the bare SnO2 anode material. A high charge capacity above 700 mAh g−1 can be achieved with a satisfying 95.6% retention after 50 cycles at a current density of 500 mA g−1, superior to reserved 126 mAh g−1 and a much lower 16.8% retention of the bare SnO2 anode. XRD pattern and HRTEM images of the cycled SnO2@rGO anode material verify the expected oxidation of Sn to SnO2 at the fully-charged state in the 50th cycle. In addition, FESEM and TEM images reveal the well-preserved free-standing structure after cycling, which accounts for high reversible capacity and excellent cycling stability of such a SnO2@rGO anode. This work provides a promising SnO2-based anode for high-capacity lithium-ion batteries, together with an effective fabrication adoptable to prepare different free-standing composite materials for device applications.https://www.frontiersin.org/article/10.3389/fchem.2019.00878/fullSnO2rGOanti-solvent-assisted precipitationfree-standing anodelithium-ion battery |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shuli Jiang Shuli Jiang Ruiming Huang Wenchang Zhu Wenchang Zhu Xiangyi Li Xiangyi Li Yue Zhao Yue Zhao Zhixiang Gao Zhixiang Gao Lijun Gao Lijun Gao Jianqing Zhao Jianqing Zhao |
spellingShingle |
Shuli Jiang Shuli Jiang Ruiming Huang Wenchang Zhu Wenchang Zhu Xiangyi Li Xiangyi Li Yue Zhao Yue Zhao Zhixiang Gao Zhixiang Gao Lijun Gao Lijun Gao Jianqing Zhao Jianqing Zhao Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance Frontiers in Chemistry SnO2 rGO anti-solvent-assisted precipitation free-standing anode lithium-ion battery |
author_facet |
Shuli Jiang Shuli Jiang Ruiming Huang Wenchang Zhu Wenchang Zhu Xiangyi Li Xiangyi Li Yue Zhao Yue Zhao Zhixiang Gao Zhixiang Gao Lijun Gao Lijun Gao Jianqing Zhao Jianqing Zhao |
author_sort |
Shuli Jiang |
title |
Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance |
title_short |
Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance |
title_full |
Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance |
title_fullStr |
Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance |
title_full_unstemmed |
Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance |
title_sort |
free-standing sno2@rgo anode via the anti-solvent-assisted precipitation for superior lithium storage performance |
publisher |
Frontiers Media S.A. |
series |
Frontiers in Chemistry |
issn |
2296-2646 |
publishDate |
2019-12-01 |
description |
Metal oxides have been attractive as high-capacity anode materials for lithium-ion batteries. However, oxide anodes encounter drastic volumetric changes during lithium ion storage through the conversion reaction and alloying/dealloying processes, leading to rapid capacity decay and poor cycling stability. Here, we report a free-standing SnO2@reduced graphene oxide (SnO2@rGO) composite anode, in which SnO2 nanoparticles are tightly wrapped within wrinkled rGO sheets. The SnO2@rGO sheet is assembled in high porosity via an anti-solvent-assisted precipitation of dispersed SnO2 nanoparticles and graphene oxide sheets in the distilled water, followed by the filtration and post-annealing processes. Significantly enhanced lithium storage performance has been obtained of the SnO2@rGO anode compared with the bare SnO2 anode material. A high charge capacity above 700 mAh g−1 can be achieved with a satisfying 95.6% retention after 50 cycles at a current density of 500 mA g−1, superior to reserved 126 mAh g−1 and a much lower 16.8% retention of the bare SnO2 anode. XRD pattern and HRTEM images of the cycled SnO2@rGO anode material verify the expected oxidation of Sn to SnO2 at the fully-charged state in the 50th cycle. In addition, FESEM and TEM images reveal the well-preserved free-standing structure after cycling, which accounts for high reversible capacity and excellent cycling stability of such a SnO2@rGO anode. This work provides a promising SnO2-based anode for high-capacity lithium-ion batteries, together with an effective fabrication adoptable to prepare different free-standing composite materials for device applications. |
topic |
SnO2 rGO anti-solvent-assisted precipitation free-standing anode lithium-ion battery |
url |
https://www.frontiersin.org/article/10.3389/fchem.2019.00878/full |
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